Journal ArticleDOI
SYNTHESIS OF REACTIVITY OF λ5-PHOSPHAZENES. USES AS SYNTHETIC INTERMEDIATES
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This article is published in Organic Preparations and Procedures International.The article was published on 1991-02-01. It has received 86 citations till now. The article focuses on the topics: Reactivity (chemistry).read more
Citations
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The aza-Wittig reaction: an efficient tool for the construction of carbon–nitrogen double bonds
Francisco Palacios,Concepción Alonso,Domitila Aparicio,Gloria Rubiales,Jesús M. de los Santos +4 more
TL;DR: Recent advances in the aza-Wittig reaction of phosphazene derivatives with several carbonyl compounds are reviewed in this article, where the most important applications of this reaction are the synthesis of a wide range of acyclic and heterocyclic compounds, ranging from simple moncyclic compounds to complex polycyclic and macrocyclic systems.
Journal ArticleDOI
Synthesis of β-Aminophosphonates and -Phosphinates
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Recent advances in synthetic applications of azadienes
Journal ArticleDOI
Linear, cyclic and polymeric phosphazenes
TL;DR: An assessment of the diversity of phosphazene chemistry is presented in this paper with an emphasis on recent developments and their significance Fundamental properties of the phosphazenes are examined such as structure, nomenclature and bonding, and various synthetic procedures are catagorized.
Journal ArticleDOI
Alcohols for the α-Alkylation of Methyl Ketones and Indirect Aza-Wittig Reaction Promoted by Nickel Nanoparticles
TL;DR: Nickel nanoparticles have been found to activate primary alcohols used for the α-alkylation of ketones or in indirect aza-Wittig reactions as mentioned in this paper, and a reaction mechanism is proposed on the basis of some deuteration experiments.
References
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Journal ArticleDOI
The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products
TL;DR: In this article, a reagent formed by combining diethyl azodicarboxylate (DEAD) and triphenylphosphine (TPP) could be utilized in the intermolecular dehydration between an alcohol and various acidic components such as carboxylic acids, phosphoric diesters, imides, and active methylene compounds.
Journal ArticleDOI
Comprehensive organic chemistry : the synthesis and reactions of organic compounds
Bull. Soc. Chim. Fr.
G. Hugel,G. Ourisson,J. Bye,J Miquel,D. P. Funeriu,Y He,H Bister,J-M Lehn,M Mousseron,J. M. Kamenka,Darvich +10 more
Journal ArticleDOI
The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects
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