Journal ArticleDOI
Synthesis, spectral characterization and electrochemical studies of mixed-ligand complexes of platinum(II) with 2-(arylazo)pyridines and catechols. Single-crystal X-ray structure of dichloro{2-(phenylazo) pyridine}platinum(II)
Goutam Kumar Rauth,Sanjib Pal,Debasis Das,Chittaranjan Sinha,Alexander M.Z. Slawin,J. Derek Woollins +5 more
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TLDR
In this article, the reaction of 2-(arylazo)pyridines, RH4C6NNC5H4N with K2PtCl4 in 1:2 boiling acetonitrile-water affords orange-red complexes of the type Pt(aap)Cl2 (2).About:
This article is published in Polyhedron.The article was published on 2001-03-01. It has received 52 citations till now. The article focuses on the topics: Semiquinone.read more
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Recent advances on the chemistry of transition metal complexes of 2-(arylazo)pyridines and its arylamino derivatives
TL;DR: Recent advancement on the redox properties of a selection of transition metal complexes of the azoaromatic ligands: bidentate L(1) [2-(arylazo)pyridine] and tridentate HL(2) [ 2-(aminoarylphenylazo) pyridine) are described and compared.
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Platinum(II) diimine complexes with catecholate ligands bearing imide electron-acceptor groups: synthesis, crystal structures, (spectro)electrochemical and EPR studies, and electronic structure.
TL;DR: Overall, the Pt(bpy*)(cat-imide) complexes are electrochromic compounds in which a series of stepwise reversible redox processes in the potential range from 0.2 to -2 V (vs Fc (+)/Fc) leads to tuneable absorbencies between 300 and 850 nm.
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Combining two non-innocent ligands in isomeric complexes [Pt(pap)mQn]0 (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone
TL;DR: Isomeric complexes of platinum, which contain two non-innocent ligands, are reported, which make it possible to separate two different positional isomers.
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Synthesis, spectroscopy and redox chemistry of bis(n-aryl-3,5-di-tert-butylsalicylaldiminato)copper(II) complexes
TL;DR: In this paper, a series of new bis(N-aryl-3,5-di-tert-butylsalicylaldiminato)copper(II) complexes (I), prepared from 3-5-detert-Butyl salicylaldehyde and mono-substituted anilines, and their spectroscopic properties as well as electrochemistry and reactivity toward PPh3 are described.
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Structures, Redox and Spectroscopic Properties of PdII and PtII Complexes Containing an Azo Functionality
TL;DR: The complexes [PdCl2(pap)] and [PtCl2pap] (1) were synthesized by treating PdCl 2 with pap and characterized by 1H NMR spectroscopy and elemental analysis as mentioned in this paper.
References
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
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Transition metal complexes of o-benzoquinone, o-semiquinone, and catecholate ligands
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Crystal Structure of the Anticancer Drug Cisplatin Bound to Duplex DNA
TL;DR: In this article, the X-ray crystal structure of the cisplatin-modified double-strand DNA dodecamer was solved to a resolution of 2.6 A (R = 0.203, R-free = 0., and Z = 2.245).
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Electrochemical studies of ruthenium compounds part I. Ligand oxidation levels
TL;DR: In this paper, the authors present des resultats d'etude par les techniques electrochimiques et spectrometriques, and present an overview of the results.