Journal ArticleDOI
Systematic study of the solvent extraction of metal β-diketonates
J. Starý,Eduard Hladký +1 more
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In this paper, the extraction of 30 metals (Be, Mg, Ca. Sr, Ba, Sc, La, Ti, Zr, Th, Cr, Mo, U, Mn, Co, Fe, Ni, Pd, Cu, Ag, Zn, Cd, Hg, Al, Ga, In, Tl, Sn, Pb and Bi) by solutions of acetylacetone, benzoylacetone and dibenzoylmethane in benzene was studied in relation to the pH values for extraction.About:
This article is published in Analytica Chimica Acta.The article was published on 1963-01-01. It has received 150 citations till now. The article focuses on the topics: Acetylacetone & Dibenzoylmethane.read more
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Mesostructured hybrid organic–inorganic thin films
TL;DR: In this article, the authors discuss the design and different synthetic routes that lead to hybrid thin films that have a periodically organized porosity, the role of the organic functionality and the resulting mesophase, the comparison between one-pot and post-synthesis approaches and the applications domain of this mesostructured hybrid film are described and discussed.
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Metal chelates of fluorinated 1,3-diketones and related compounds
TL;DR: In this article, der Ubersichtsartikel befast sich mit der Darstellung, der Rontgenstrukturanalyse und den spektroskopischen Eigenschaften von uber 80 Metallchelaten von fluorierten 1,3-Diketonen.
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Redox speciation of plutonium
TL;DR: In this article, the importance of the insolubility of Pu(V)O 2 + is discussed, and the merits and limitations of some chemical separation techniques used to study redox speciation of plutonium are presented, and recommendations made for obtaining reliable oxidation state distribution data.
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Advanced selective optical sensors based on periodically organized mesoporous hybrid silica thin films
Lionel Nicole,Cédric Boissière,David Grosso,Peter Hesemann,Joël J. E. Moreau,Clément Sanchez +5 more
TL;DR: Mesoporous thin films functionalized with silylated [small beta]-diketone compounds with symmetry mesostructure dependent on the probe quantity were used as fast uranyl species sensors with high selectivity and sensitivity.
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Separation of actinides in different oxidation states from neutral solutions by solvent extraction
Akira Saito,Gregory R. Choppin +1 more
TL;DR: In this article, the authors used dibenzoylmethane extractant for fast, efficient separation of actinide elements in the III, IV, V, and VI oxidation states in aqueous solutions of neutral pH.
References
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Systematic study of the solvent extraction of metal oxinates
TL;DR: In this paper, the effects of pH, oxine concentration and water-soluble complexing agents (oxalic acid, tartaric acid and hydrocyanic acid) have been investigated.
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Some relationships amoung the stabilities of metal complexes
H. Irving,H. Rossotti +1 more
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