Journal ArticleDOI
The addition to and alkylation of naphthalene by tert-butyllithium. Kinetics and mechanism
R. L. Eppley,J. A. Dixon +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1968-03-01. It has received 25 citations till now. The article focuses on the topics: Alkylation.read more
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Journal ArticleDOI
Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms
Journal ArticleDOI
Nucleophilic dearomatizing (DNAr) reactions of aromatic C,H-systems. A mature paradigm in organic synthesis.
Fernando López Ortiz,María José Iglesias,Ignacio Fernández,Carmen M. Andujar Sanchez,Gloria Ruiz Gomez +4 more
Journal ArticleDOI
Chiral oxazolines and their legacy in asymmetric carbon-carbon bond-forming reactions.
TL;DR: The studies performed with chiral oxazolines as vehicles for a number of C-C bond-forming reactions are traced back to the early 1970s, with the main source of chirality derived from chiral, nonracemic amino alcohols which, themselves, were prepared from amino acids.
Book ChapterDOI
4.4 – Carbometallation of Alkenes and Alkynes
TL;DR: Carbometallation reactions are reactions which result in the addition of the carbon-metal bond of an organometallic (1) across a carbon-carbon multiple bond (2) leading to a new organometal (3).
Journal ArticleDOI
Nucleophilic Aromatic Substitution Reactions of 1,2‐Dihydro‐1,2‐Azaborine
TL;DR: Could go either way: the addition of nucleophiles to the parent 1, 2-dihydro-1,2-azaborine and subsequent quenching with an electrophile generates novel substituted 1,3-azabine derivatives.
Related Papers (5)
Reaction intermediates in the alkylation of pyridine with tert-butyllithium
Nucleophilic attack leading to addition of alkyllithium reagents to aromatic hydrocarbons
Alkylation of Aromatic Hydrocarbons by Alkyllithium Reagents
Joseph A. Dixon,David H. Fishman +1 more