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The anomeric effect
Eusebio Juaristi,Gabriel Cuevas +1 more
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TLDR
This chapter discusses the history and applications of the Anomeric Effect in Organic Synthesis, and some of the applications can be found in the literature on endoelectronic effects of the anomeric effect.Abstract:
Historical Aspects and Definitions Origin and Consequences of the Anomeric Effect Theoretical Studies of the Anomeric Effect Stereoelectronic Effects Associated with the Anomeric Effect Endo and Exo Anomeric Interactions The Enthalpic Anomeric Effect Second- and Lower-Row Anomeric Interactions The Reverse Anomeric Effect The Kinetic Anomeric Effect Applications of the Anomeric Effect in Organic Synthesisread more
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TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile Chiral Auxiliaries
TL;DR: TADDOLs are the most effective doping agents known for phase transformations of achiral (nematic) into chiral (cholesteric) liquid crystals and show further unusual characteristics that make them useful for applications in material science and supramolecular chemistry.
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QM/MM Methods for Biological Systems
Hans Martin Senn,Walter Thiel +1 more
TL;DR: In this article, the state of the art of combined quantum-mechanics/molecular mechanics (QM/MM) methods with a focus on biomolecular systems is reviewed.
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Small Molecule Conformational Preferences Derived from Crystal Structure Data. A Medicinal Chemistry Focused Analysis
TL;DR: Based on torsion angle distributions of frequently occurring substructures, conformation preferences of druglike molecules are presented, accompanied by a review of the relevant literature and properties of aryl ring substituents are discussed.
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Steric effect: A quantitative description from density functional theory
TL;DR: A few molecular systems involving conformation changes and chemical reactions have been investigated to examine the relative contribution of the steric and other effects, providing insights for a few controversial topics from a different perspective.