Journal ArticleDOI
The formation of polyaniline and the nature of its structures
Reads0
Chats0
TLDR
A scheme of interrelated structures which accounts for all the spectroscopic and conductometric observations, together with a set of equations summarizing the chemical transformations involved, is proposed in this article.About:
This article is published in Polymer.The article was published on 1996-01-01. It has received 293 citations till now. The article focuses on the topics: Polyaniline.read more
Citations
More filters
Journal ArticleDOI
Polyaniline: a polymer with many interesting intrinsic redox states
TL;DR: The ability of aniline polymers to exist in a large number of intrinsic redox states makes them a unique and interesting class of polymeric materials as mentioned in this paper, and a number of fine reviews on the synthesis, physicochemical and electrochemical properties of the polymer have also appeared during this period.
Journal ArticleDOI
Polyaniline nanostructures and the role of aniline oligomers in their formation
TL;DR: A review of PANI nanostructures can be found in this paper, where a model of a flowing template combined with a helical nanotubular growth is proposed to account for the formation of nanotubes.
Journal ArticleDOI
The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures
Irina Sapurina,Jaroslav Stejskal +1 more
TL;DR: A molecular mechanism for the oxidation of aniline is proposed in this paper, which explains the specific features of polyaniline oligomerization and polymerization in various acidity ranges.
Journal ArticleDOI
Evolution of polyaniline nanotubes: The oxidation of aniline in water
Miroslava Trchová,Ivana Sedĕnková,Elena N. Konyushenko,Jaroslav Stejskal,Petr Holler,Gordana Ćirić-Marjanović +5 more
TL;DR: Gel-permeation chromatography indicates that aniline oligomers are produced at first at high pH, while polyaniline follows after the pH becomes sufficiently low, which indicates that the kinetic course of polymerization is controlled by the acidity level.
Journal ArticleDOI
FTIR spectroscopic and conductivity study of the thermal degradation of polyaniline films
TL;DR: In this article, the thermal degradation of polyaniline films polymerized in situ on silicon windows, and protonated with hydrochloric, sulfuric or phosphoric acid, has been studied by FTIR spectroscopy.
References
More filters
Journal ArticleDOI
Polyaniline, a novel conducting polymer. Morphology and chemistry of its oxidation and reduction in aqueous electrolytes
TL;DR: The emeraldine salt form of polyaniline can be synthesized electrochemically as a film exhibiting a well defined fibrillar morphology closely resembling that of polyacetylene as mentioned in this paper.
Journal ArticleDOI
All-polymer field-effect transistor realized by printing techniques
TL;DR: A field-effect transistor has been fabricated from polymer materials by printing techniques, which shows high current output, and opens the way for large-area, low-cost plastic electronics.
Journal ArticleDOI
Polyaniline: A historical survey
TL;DR: A survey of the literature available on conducting organic polyaniline can be found in this paper, where the authors provide a survey of some of the most recent work on polyanILine.
Journal ArticleDOI
Dimercaptan–polyaniline composite electrodes for lithium batteries with high energy density
TL;DR: In this paper, the authors developed a rechargeable lithium battery with a composite organic cathode based on a mixture of a dimercaptan and polyaniline, which can be repeatedly charged to near its theoretical limit and discharged.
Journal ArticleDOI
Electrochemistry of Conductive Polymers II . Electrochemical Studies on Growth Properties of Polyaniline
David E. Stilwell,Su-Moon Park +1 more
TL;DR: In this article, the growth rate of polyaniline (PA) is characterized as autocatalytic and the electrochemical growth may be characterized as first order in aniline concentration, depending on the amount of PA film on the electrode and the number of potential cycles.
Related Papers (5)
POLYANILINE. PREPARATION OF A CONDUCTING POLYMER (IUPAC Technical Report)
‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime
J. C. Chiang,Alan G. MacDiarmid +1 more