Journal ArticleDOI
The rate coefficients for several ternary association reactions at thermal energies
Nigel G. Adams,David Smith +1 more
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TLDR
In this paper, the rate coefficients for ternary association reactions of CH 3 + and CD 3 + with H 2, N 2, O 2 CO and CO 2 N 2 + with N 2 and D 2 have been measured within the temperature range 80-520 K in helium buffer gas.About:
This article is published in Chemical Physics Letters.The article was published on 1981-05-01. It has received 74 citations till now. The article focuses on the topics: Ternary operation & Buffer gas.read more
Citations
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Journal ArticleDOI
Ion-Molecule Reactions
TL;DR: McDaniel et al. as mentioned in this paper presented a series of experiments in Atomic and Molecular Collisional Processes (AOMCPs) and showed that collisional processes can be solved by ion reactions.
Book ChapterDOI
The Selected Ion Flow Tube (Sift): Studies of Ion-Neutral Reactions
David Smith,Nigel G. Adams +1 more
TL;DR: The Selected Ion Flow Tube (SIFT) as mentioned in this paper is an extension of the Flowing Afterglow (FA) technique for ion-neutral reactions under truly thermal conditions, where the ion source gas is excluded from the carrier gas and therefore from the reaction zone.
Journal ArticleDOI
Study of the reactions N+2+2N2→N+4+N2 and O+2+2O2→O+4+O2 from 20 to 160 K by the CRESU technique
TL;DR: In this article, the rate coefficients k1 and k2 for the association reaction N+2+2 N2→k1N+4+N2 and O+ 2+2 O2 →k2O+4 +O2 in the temperature range 20-160 K, using a supersonic jet apparatus (CRESU), were determined.
Journal ArticleDOI
Advances in Determining the Absolute Proton Affinities of Neutral Organic Molecules in the Gas Phase and Their Interpretation: A Theoretical Account
TL;DR: Evidence provided by this Review shows that the coalescence of experimental and theoretical/computational work is not only highly desirable for that purpose, but, in fact, greatly needed.
Book ChapterDOI
Experimental studies on cluster ions
Tilmann D. Märk,A.W. Castleman +1 more
TL;DR: Cluster ions are a nonrigid assembly of components having properties between those of large gas phase molecules and the bulk condensed state as discussed by the authors, and they are used for fuel injection into fusion reactors and cluster ions are also present in other high-temperature systems such as those designed as sources of energy employing magnets and hydrodynamics.
References
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Journal ArticleDOI
Ion-Neutral Reaction-Rate Constants Measured in Flow Reactors through 1977
TL;DR: The rate constants of ion-neutral reactions with flowing-after-glow, flow-drift, and selected-ion flow tubes have been compiled in this paper, where the data for both positive and negative ion reactions are included and arranged for access by the reactant ion, reactant neutral, and product ion.
Journal ArticleDOI
Ion-Molecule Reactions
TL;DR: McDaniel et al. as mentioned in this paper presented a series of experiments in Atomic and Molecular Collisional Processes (AOMCPs) and showed that collisional processes can be solved by ion reactions.
Journal ArticleDOI
Laboratory studies of isotope fractionation in the reactions of C/+/ and HCO/+/ with CO - Interstellar implications
David Smith,Nigel G. Adams +1 more
Journal ArticleDOI
A statistical theory of three‐body ion–molecule reactions
TL;DR: In this paper, a theory of three-body ion-molecule reactions at low pressures is presented, which incorporates the principle of detailed balancing, and agreement between theory and recent experiments on a variety of polyatomic reactive systems is assessed and found to be satisfactory.