Journal ArticleDOI
The Reaction of OH Radicals with 1,1‐di‐, tri‐ and tetrachloroethylene
K. Kirchner,D. Helf,P. Ott,S. Vogt +3 more
- Vol. 94, Iss: 1, pp 77-83
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TLDR
In this article, the authors investigated the kinetics and product formation of the homogeneous gas-phase reactions of the OH radical with 1,1-di, tri-and tetrachloroethylene, in the pressure range of 0.5-5.6 mbar.Abstract:
The kinetics and product formation of the homogeneous gas-phase reactions of the OH radical with 1,1-di-, tri- and tetrachloroethylene were investigated at temperatures between 298–459 K, in the pressure range of 0.5–5.6 mbar. Measurements were made in a discharge-flow apparatus, using helium as the carrier gas. The OH radical and the reaction products were detected by mass spectrometry. The rate constants were observed to be pressure independent in the case of 1,1-di- and tetrachloroethylene but slightly pressure dependent in the case of trichloroethylene. The temperature dependencies can be expressed by the Arrhenius equation (in units of 1012 cm3 mol−1 s−1).
k(T) = (0.136 ± 0.016) exp[(9.5 ± 0.4) kJ mol−1/RT] for 1,1-dichloroethylene,
k(T) = (0.470 ± 0.051) exp[(2.0 ± 0.5) kJ mol−1/RT] for trichloroethylene, and
k(T) = (3.33 ± 0.19) exp[−(8.6 ± 0.1) kJ mol−1/RT] for tetrachloroethylene.
The major products are: CH2OH — CCl2 for 1,1-dichloroethylene; 2,2-dichloroethenol and Cl for trichloroethylene; trichloroethenol, dichloroacetyl chloride, Cl, CHCl2 and phosgene for tetrachloroethylene.read more
Citations
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Journal ArticleDOI
Selective detection of isomers with photoionization mass spectrometry for studies of hydrocarbon flame chemistry
T.A. Cool,Koichi Nakajima,T Mostefaoui,Fei Qi,Andrew McIlroy,Phillip R. Westmoreland,Matthew E. Law,Lionel Poisson,Darcy S. Peterka,Musahid Ahmed +9 more
TL;DR: In this article, the first use of synchrotron radiation for flame-sampling photoionization mass spectrometry (PIMS) was reported, which is the first application of Synchronized Light Source (SLS) for PIMS.
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Kinetic studies of oxidation of ethylene over a TiO2 photocatalyst
TL;DR: In this article, the photo-assisted catalytic degradation of ethylene was studied in the tubular photoreactor packed with TiO2 pellets prepared by sol-gel method, and the dependence of the reaction rate on the light intensity, feed composition (ethylene, oxygen and water vapor) and temperature were investigated.
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Photocatalytic degradation of trichloroethylene in water using TiO2 pellets.
TL;DR: In batch experiments with TiO2 powders, Degussa P-25 is the most active photocatalyst, which indicates that specific surface area is not an important factor controlling the photocatalytic activity in aqueous solutions.
Journal ArticleDOI
The thermal decomposition of peroxyacetic nitric anhydride (PAN) and peroxymethacrylic nitric anhydride (MPAN)
TL;DR: In this article, the rate coefficients of thermal decomposition of peroxyacetic nitric anhydride (PAN) and peroxymethacrylic (MPAN) were measured over the temperature range of 302-323 K. The resulting Arrhenius expressions were k = 1017.4±0.4 exp(−28.5 ± 0.5/RT) for PAN, and k = 6.2± 0.7 exp (−26.8 ± 1.0/RT), where the activation energy is in Kcal/mol
References
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Journal ArticleDOI
Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions
Journal ArticleDOI
Kinetics and mechanisms of the gas-phase reactions of ozone with organic compounds under atmospheric conditions
Journal ArticleDOI
Evaluation of Kinetic and Mechanistic Data for Modeling of Photochemical Smog
Roger Atkinson,Alan C. Lloyd +1 more
TL;DR: In this article, a critical evaluation of the rate constants, mechanisms, and products of selected atmospheric reactions of hydrocarbons, nitrogen oxides, and sulfur oxides in air is presented.
Journal ArticleDOI
Mass-spectrometric study of the reactions of the hydroxyl radical with ethylene, propylene, and acetaldehyde in a discharge-flow system
Journal ArticleDOI
Atmospheric reactions of chloroethenes with the OH radical
TL;DR: In this paper, the authors investigated the kinetics and products of the homogeneous gas-phase reactions of the OH radical with the chloroethenes at 298 ± 2 K and atmospheric pressure, using a relative rate technique and ethane as a scavenger for the chlorine atoms produced in these OH radical reactions.
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