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The Reactions of Primary Nitroparaffins with Isocyanates1

Teruaki Mukaiyama, +1 more
- 01 Oct 1960 - 
- Vol. 82, Iss: 20, pp 5339-5342
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This article is published in Journal of the American Chemical Society.The article was published on 1960-10-01. It has received 503 citations till now. The article focuses on the topics: Nitroparaffins & Thesaurus (information retrieval).

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A Facile Synthesis of 3,4-Disubstituted Isoxazole Derivatives by Regioselective Cleavage of Pyrano[3,4-C]Isoxazoles with Boron Trihalide

TL;DR: Pyrano[3,4-c]isoxazoles 4 were efficiently prepared by the intramolecular nitrile oxide-alkyne cycloaddition following the addition of sodium alkoxide to nitroalkene as mentioned in this paper.
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NMR/NOE elucidation of the stereostructure of cycloadducts of acetonitrile oxide with norbornane/ene-fused dihydro-oxazines†

TL;DR: Norbornane-di-endo and -di-exo-fused dihydro-1,3-oxazines underwent cycloaddition with in situ prepared acetonitrile oxide to yield tetracyclic 1,2,4-oxadiazolines as mentioned in this paper.
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A convenient one-pot synthesis of 3,5-diarylisoxazoles via oxidative cyclisation using catalytic CuBr2 and oxone

TL;DR: A facile one-pot synthesis of 3,5-diarylisoxazoles from α,β-unsaturated ketones and hydroxylamine hydrochloride is reported in this article.
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Unsaturated germanes and stannanes in the synthesis of nitrogen-containing heterocycles by [2+3]-cycloaddition

TL;DR: Literature data and results of fundamental investigations on synthetic methods and chemical reactions of the products of 1,3-dipolar additions to unsaturated germanes and stannanes are reviewed in this article.
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Target alcohol/phenol release by cyclative cleavage using glycine as a safety catch linker.

TL;DR: In this paper, the utility of glycine as a safety catch linker for the immobilization of alcohols and phenols to the solid support is demonstrated by performing a variety of synthetic transformations.