Journal ArticleDOI
The remarkable decarbonylation of chromium, molybdenum, and tungsten hexacarbonyls supported on silica and the nature of these materials as heterogeneous catalysts
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This article is published in Inorganic Chemistry.The article was published on 1979-06-01. It has received 64 citations till now. The article focuses on the topics: Decarbonylation & Molybdenum.read more
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Journal ArticleDOI
Chemical vapor deposition methods for the controlled preparation of supported catalytic materials.
Journal ArticleDOI
Metal-support interactions between iron and titania for catalysts prepared by thermal decomposition of iron pentacarbonyl and by impregnation
TL;DR: The metal-support interaction between iron and titania, which is initiated by reduction at 800 K and is responsible for the changes in ammonia synthesis kinetics, is due to titanium species at the surface of the metallic iron particles as mentioned in this paper.
Book ChapterDOI
A Review of the Phillips Supported Chromium Catalyst and Its Commercial Use for Ethylene Polymerization
TL;DR: The Phillips supported chromium catalyst is used to produce some 40% to 50% of the world's high-density polyethylene as discussed by the authors, and the chemistry of this important catalyst is reviewed from an industrial perspective, on the basis of more than half a century of commercial experience, as well as published research.
Book ChapterDOI
Nature and Estimation of Functional Groups on Solid Surfaces
H.P. Boehm,Helmut Knözinger +1 more
TL;DR: The interaction of the adsorptive with the adsorbent can very greatly in nature, i.e. from weak interaction by van der Waals forces, leading to physisorption, to strong chemical bonding or chemisorsorption as mentioned in this paper.
Book ChapterDOI
Chemical Design Surfaces for Active Solid Catalysts
TL;DR: In this article, the authors focus on the chemical design surfaces for active solid catalysts that can be regarded as a promising and scientific way to prepare well-defined active surfaces with excellent catalytic properties as well as to elucidate reaction mechanisms.
Related Papers (5)
Catalysts of supported iron derived from molecular complexes containing one, two, and three iron atoms
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