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Journal ArticleDOI

The Structure of N‐(1‐Deoxy‐β‐D‐fructopyranos‐1‐yl)‐L‐proline Monohydrate (“D‐Fructose‐L‐proline”) and N‐(1,6‐Dideoxy‐α‐L‐fructofuranos‐1‐yl)‐L‐proline (“L‐Rhamnulose‐L‐proline”)

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TLDR
In this paper, the crystal structure analysis of N−(1−deoxy−β−D−fructopyranos−1−yl)−L−proline monohydrate is presented.
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This article is published in Journal of Carbohydrate Chemistry.The article was published on 2007-06-21. It has received 13 citations till now. The article focuses on the topics: Pyranose & Furanose.

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Book ChapterDOI

1-Amino-1-deoxy-d-fructose (“Fructosamine”) and its Derivatives

TL;DR: The scope of the knowledge on and applications of fructosamine-related molecules in chemistry, food, and health sciences, as reflected mostly in publications within the past decade are assessed.
Journal ArticleDOI

Structure-reactivity relationship of Amadori rearrangement products compared to related ketoses.

TL;DR: It could be shown exemplarily that the Amadori compound N-(1-deoxy-d-fructos-1-yl)-l-proline exhibits much higher isomerisation rates than d-fructose, which can be explained by C-1 substituent mediated intramolecular catalysis.
Journal ArticleDOI

Stabilization of the Acyclic Tautomer in Reducing Carbohydrates

TL;DR: Crystal structures of several acyclic dfructose keto tautomers are obtained, for the first time, from d-fructosamine derivatives 6 and 8, and similarities between the conformations of the carbohydrate part of this compound and the xylo-pentose substrate in the active site of d-xylose isomerase are revealed.
Journal ArticleDOI

Structure of D-Fructosamine Hydrochloride and D-Fructosamine Hydroacetate

TL;DR: In this paper, the crystal structure analyses of 1-deoxy-β -D-fructopyranos-1-ylamine hydrochloride (1) and -hydroacetate (2) salts are reported.
References
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Journal ArticleDOI

General definition of ring puckering coordinates

TL;DR: In this article, a unique mean plane is defined for a general monocyclic puckered ring, which is described by amplitude and phase coordinates which are generalizations of those introduced for cyclopentane by Kilpatrick, Pitzer, and Spitzer.
Journal ArticleDOI

X-Seed — A Software Tool for Supramolecular Crystallography

TL;DR: X-Seed as mentioned in this paper is a software tool for X-ray crystallographers and runs under any of the 32-bit Microsoft Windows operating systems including 95, 98, Millennium Edition, 2000 and XP.
Journal ArticleDOI

Exact method for the calculation of pseudorotation parameters P, τm and their errors. A comparison of the Altona–Sundaralingam and Cremer–Pople treatment of puckering of five-membered rings

TL;DR: In this article, an exact procedure for obtaining the A-S parameters τm, P that correspond to the amplitude and phase of the Fourier wave of period 4π/5 was presented.
Journal ArticleDOI

Recent Advances in the Chemistry of Strecker Degradation and Amadori Rearrangement: Implications to Aroma and Color Formation

TL;DR: In this paper, the role of Amadori rearrangement in controlling the balance among four critically important key intermediates: α-dicarbonyl, α-hydroxy carbonyl and 2-amino carbonyls during the Maillard reaction and hence control relative importance of aromagenic versus chromogenic pathways.
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