Journal ArticleDOI
Thermal analysis of chemically synthesized polyaniline and effects of thermal aging on conductivity
Yen Wei,Kesyin F. Hsueh +1 more
TLDR
In this paper, the HCl-doped polyaniline showed three major weight losses at around 100, 200, and 500°C which are assigned to removal of H2O and HCl, and decomposition of the polymer, respectively.Abstract:
Thermal characteristics of chemically synthesized polyaniline with various dopants have been studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), infrared spectroscopy, gel-permeation chromatography (GPC), and chemical titration. The HCl-doped polyaniline shows three major weight losses at around 100, 200, and 500°C which are assigned to removal of H2O and HCl, and decomposition of the polymer, respectively. Thermal aging of the HCl-doped polyaniline performed at 100, 150, and 200°C for various periods of time results in a decrease in conductivity. After the thermal treatments, the polymer can be re-doped with HCl to partially recover the conductivity. However, both the conductivity and the doping level cannot be restored to the level of the original materials owing probably to changes in morphology, crosslinking, or other chemical reactions.read more
Citations
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Journal ArticleDOI
Polyaniline: a polymer with many interesting intrinsic redox states
TL;DR: The ability of aniline polymers to exist in a large number of intrinsic redox states makes them a unique and interesting class of polymeric materials as mentioned in this paper, and a number of fine reviews on the synthesis, physicochemical and electrochemical properties of the polymer have also appeared during this period.
Journal ArticleDOI
Polyaniline nanostructures and the role of aniline oligomers in their formation
TL;DR: A review of PANI nanostructures can be found in this paper, where a model of a flowing template combined with a helical nanotubular growth is proposed to account for the formation of nanotubes.
Journal ArticleDOI
Some aspects of preparation methods and properties of polyaniline blends and composites with organic polymers
TL;DR: In this paper, generalized approaches for the preparation of polyaniline materials are reviewed, focusing on features that determine properties of the final composites/blends, and two distinct groups of synthetic methods based on aniline polymerization either (1) in the presence of or inside a matrix polymer or (2) the blending of a previously prepared PANI with a matrix polymers.
Journal ArticleDOI
Polyaniline/Au composite hollow spheres: synthesis, characterization, and application to the detection of dopamine.
TL;DR: It was found that the electrical conductivity of the PANI/Au composite hollow spheres was more than 3 times higher than that of the pure PANI hollow spheres.
Journal ArticleDOI
Self-assembly approach for the synthesis of electro-magnetic functionalized Fe3O4/polyaniline nanocomposites: Effect of dopant on the properties
TL;DR: In this paper, a plausible mechanism for the formation of the nanocomposites (NCs) is presented, in which two different types of dopants, organic acids (camphorsulfonic acid (CSA) and p-toluenesulfonic acids (TSA)) and inorganic acid (hydrochloric acid) are used as a micellar template, whereas micelle formation is absent in the case of HCl.
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