Journal ArticleDOI
Topochemistry of thermal decompositions of solids
TLDR
In this article, the authors systematically consider the factors responsible for localization and autolocalization of thermal decomposition processes of solids and show the specificity and complexity of nucleation and nuclei growth in topochemical processes.About:
This article is published in Thermochimica Acta.The article was published on 1986-05-01. It has received 29 citations till now. The article focuses on the topics: Thermal decomposition & Nucleation.read more
Citations
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Solid-State Kinetic Models: Basics and Mathematical Fundamentals
Ammar Khawam,Douglas R. Flanagan +1 more
TL;DR: This work summarizes commonly employed models and presents their mathematical development as nucleation, geometrical contraction, diffusion, and reaction order.
Journal ArticleDOI
Thermal decomposition of ammonium perchlorate
TL;DR: In this article, the authors summarize literature data on thermal decomposition of ammonium perchlorate and discuss the mechanism of the decomposition and various factors that influence the thermal decompositions of perchlorates.
Journal ArticleDOI
An appreciation of the chemical approach of V. V. Boldyrev to the study of the decomposition of solids
TL;DR: Boldyrev as discussed by the authors has made numerous important contributions to a wide range of chemical topics, not only limited to studies of the decompositions of solids, but also focusing on exploring, in detail, the chemical steps participating in the thermal reactions of the solids by carefully designed experiments.
Journal ArticleDOI
What can we learn about the mechanisms of thermal decompositions of solids from kinetic measurements
TL;DR: In this paper, the authors focus on the shortcomings of reaction models, originally developed for simple homogeneous reactions, which have been extended, without adequate justification, to represent heterogeneous breakdowns of crystalline reactants, and the value of complementary investigations, including microscopy, diffraction, etc., in interpreting measured rate data.
Journal ArticleDOI
Thermal decomposition under oxidative atmosphere of lignocellulosic wastes: Different kinetic methods application
TL;DR: In this article, the activation energy and the preexponential factor (A) values calculated by the DAEM, FWO and Kissinger methods were higher than those obtained by the linear multiple regression and Coast Redfern methods.
References
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Journal ArticleDOI
The thermal decomposition of potassium permanganate
E. G. Prout,F. C. Tompkins +1 more
Journal ArticleDOI
The strains produced by precipitation in alloys
TL;DR: The shape of the particle actually formed is influenced by this energy, by the degree of supersaturation of the solid solution, and by surface effects; the calculated shape is shown to agree reasonably well with that observed experimentally as discussed by the authors.
Journal ArticleDOI
On the mechanism of the decomposition of ammonium perchlorate.
P. W. M. Jacobs,A. Russell-Jones +1 more
Journal ArticleDOI
The Thermal Decomposition of Ammonium Perchlorate. II. The Kinetics of the Decomposition, the Effect of Particle Size, and Discussion of Results
L. L. Bircumshaw,B. H. Newman +1 more
TL;DR: In this paper, the energy of activation of the thermal decomposition was investigated over the temperature range 215 to 275 degrees C. The rate of decomposition increased to a maximum with decreasing particle size and then to decrease again.
Related Papers (5)
A distributed activation energy model of thermodynamically inhibited nucleation and growth reactions and its application to the β-δ phase transition of HMX
Solid-State Kinetic Models: Basics and Mathematical Fundamentals
Ammar Khawam,Douglas R. Flanagan +1 more