Journal ArticleDOI
Total syntheses of (.+-.)-seychellene and (.+-.)-cycloseychellene
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This article is published in Journal of Organic Chemistry.The article was published on 1985-07-01. It has received 14 citations till now. The article focuses on the topics: Claisen rearrangement & Wittig reaction.read more
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Book ChapterDOI
The Prins and Carbonyl Ene Reactions
TL;DR: A wide variety of carbonyl compounds undergo Lewis acid catalyzed reactions with alkenes to give homoallylic alcohol ene adducts in excellent yield with high selectivity, although in some cases γ-chloro alcohols are formed as by-products.
Journal ArticleDOI
The essential oil of patchouli, Pogostemon cablin: A review
Teris A. van Beek,Daniel Joulain +1 more
TL;DR: In this article, a review of the literature pertaining to patchouli was critically reviewed with an emphasis on the qualitative and quantitative chemical analysis of the oil but also harvesting, fermentation, drying, distillation, used analytical techniques, sensory aspects including molecules responsible for the odour, adulteration and toxicological aspects, i.e., skin sensitisation.
Journal ArticleDOI
Bioinspired intramolecular Diels-Alder reaction: a rapid access to the highly-strained cyclopropane-fused polycyclic skeleton.
TL;DR: A bioinsipred gold-catalyzed tandem Diels-Alder/Friedel-Crafts tandem reaction of an enynal and a 1,3-diene, forming the highly-strained benzotricyclo[3.2.1.0(2,7) ]octane skeleton, was reported.
Journal ArticleDOI
Is osmylation always preferring the richest double bond
Journal ArticleDOI
Stereocontrolled total synthesis of (±)-norpatchoulenol and two metabolites of patchouli alcohol, (±)-hydroxy patchouli alcohol and the corresponding (±)-carboxylic acid
TL;DR: In this paper, the first total synthesis of the two biooxidation products of patchouli alcohol and carboxylic acid has been achieved in highly stereoconcrolled manners.