Journal ArticleDOI
Trifluoroacetic acid catalysed [1,3]-rearrangement of aryl 2-halocyclohexenylmethyl ethers
TLDR
In this paper, an unusual [1, 3]-rearrangement of aryl 2-halocyclohexenylmethyl ethers promoted by trifluoroacetic acid was observed.About:
This article is published in Tetrahedron Letters.The article was published on 1998-03-12. It has received 9 citations till now. The article focuses on the topics: Claisen rearrangement & Trifluoroacetic acid.read more
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An Unexpected Thermal [1,3]-[1,3]-para Rearrangement of Chromone-3-ylmethyl Aryl Ethers: Mechanism and Application of the Intercepted [1,3]-Rearranged Intermediates to the Synthesis of cis-Homopterocarpans
Krishnan Devarajan,Somasundaram Devaraj,Kalpattu K. Balasubramanian,Shanmugasundaram Bhagavathy +3 more
TL;DR: Chromone-3-ylmethyl aryl ethers with unsubstituted ortho-positions have been found to undergo a novel domino [1,3]-[1, 3]-rearrangement to give 4′-hydroxyhomoisoflavones under thermal conditions as discussed by the authors.
Journal ArticleDOI
Synthesis of oligo-6-bromo-6-deoxy-β-cyclodextrins
TL;DR: In this paper, two methods of synthesis of oligo-6-bromo,6-deoxy-β-cyclodextrins, with use of the Vilsmeier-Haack reagent and via tosyl derivatives of β-cyclodesxtrin, were compared.
Reference EntryDOI
Tautomeric Equilibria and Rearrangements Involving Phenols
TL;DR: In this paper, Tautomeric transformations of phenols -keto-enol tautomerism and tautomechanic equilibrium -were used for rearrangements of non-Aromatic carbocycles.
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Book
The Total Synthesis of Natural Products
TL;DR: The Total Synthesis of Macrocyclic Lactones Synthesis for the Leukotrienes Synthesis as discussed by the authors, 1980 - 1986, is a classic work in the field of macrocyclic lactones.
Journal ArticleDOI
Recent advances in the chemistry and biochemistry of cannabis
Journal ArticleDOI
Clay catalyzed rearrangement of substituted allyl phenyl ethers: Synthesis of ortho-allyl phenols, chromans and coumarans
TL;DR: Montmorillonite clays catalyze the rearrangement of substituted allyl phenyl ethers to provide ortho-allyl phenols, chromans and coumarans under mild conditions as mentioned in this paper.