Journal ArticleDOI
Unified model of catalyzed and uncatalyzed decomposition of ammonium perchlorate
R.P. Rastogi,A. P. Rao,V. Syal +2 more
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TLDR
In this paper, an integrated form of the relation d γ d t = aγ−bγ 2 1+dγ where α denotes the fraction decomposed at time t and a, b, and d are constants.About:
This article is published in Combustion and Flame.The article was published on 1983-01-01. It has received 2 citations till now. The article focuses on the topics: Ammonium perchlorate & Thermal decomposition.read more
Citations
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Journal ArticleDOI
Thermal decomposition of ammonium perchlorate
TL;DR: In this article, the authors summarize literature data on thermal decomposition of ammonium perchlorate and discuss the mechanism of the decomposition and various factors that influence the thermal decompositions of perchlorates.
Journal ArticleDOI
Intrinsic Instability During Combustion of Composite Solid Propellants
R. P. Rastogi,A. P. Rao,V. Syal +2 more
TL;DR: In this article, Rastogi et al. studied the stability of a CSTR with an exothermic reaction and showed that the system is always stable if an endothermic chain reaction occurs.
References
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Journal ArticleDOI
Decomposition and combustion of ammonium perchlorate
Journal ArticleDOI
Mechanism of the decomposition of ammonium perchlorate
G S Pearson,P.W.M. Jacobs +1 more
TL;DR: In this paper, a detailed mechanism for the chemical decomposition of ammonium perchlorate is proposed, which is adaptable to a wide range of conditions; to the low-temperature decomposition, to combustion, to the catalysed decomposition and to decomposition under various reactive gases.
Journal ArticleDOI
On the mechanism of the thermal decomposition of ammonium perchlorate
Vladimir V. Boldyrev,V.V. Alexandrov,A.V. Boldyreva,V.I. Gritsan,Yu. Ya. Karpenko,O.P. Korobeinitchev,V.N. Panfilov,E.F. Khairetdinov +7 more
TL;DR: The experimental results confirming the proton-transfer mechanism of the ammonium perchlorate (AP) thermal decomposition over a wide temperature range are presented in this paper, where it is shown by use of a time-of-flight mass spectrometer that the primary products of the thermal degradation of AP are ammonia and perchloric acid.
Journal ArticleDOI
Solid state chemistry of copper chromite used as a catalyst for the burning of ammonium perchlorate/polystyrene propellants
TL;DR: In this article, the formation of copper chromite by solid-state reaction between basic copper carbonate and chromium carbonate has been investigated and the extent of reaction is 98% even when the reactants are heated for 15 min at 800 °C.
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