Journal ArticleDOI
Unusual Radical Copolymerization of Suprabulky Methacrylate with N-Hydroxysuccinmide Acrylate: Facile Syntheses of Alternating-Rich Copolymers of Methacrylic Acid and N-Alkyl Acrylamide
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In this article, a facile methodology to synthesize AB alternating-rich copolymers made of methacrylic acid (MAA) and alkyl acrylamide units was provided.Abstract:
In this work, we provide a facile methodology to synthesize AB alternating-rich copolymers made of methacrylic acid (MAA) and alkyl acrylamide units. An extremely bulky tert-alkyl methacrylate carr...read more
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AB-alternating copolymers via chain-growth polymerization: synthesis, characterization, self-assembly, and functions.
Kana Nishimori,Makoto Ouchi +1 more
TL;DR: Four topics related to alternating copolymers synthesized via chain-growth polymerization are reviewed: how to control the alternating sequence; (2) sequence characterization; (3) self-assembly; and (4) functions.
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Construction methodologies and sequence-oriented properties of sequence-controlled oligomers/polymers generated via radical polymerization
TL;DR: A review of the methodologies and concepts for sequence regulation via radical polymerization processes and the sequence-oriented properties of the resultant sequence-controlled polymers can be found in this paper.
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Lewis Pair Catalyzed Regioselective Polymerization of (E,E)-Alkyl Sorbates for the Synthesis of (AB)n Sequenced Polymers
TL;DR: In this article, N-heterocyclic olefins (NHOs) with different steric hindrance and nucleophilicity as Lewis bases were applied for 1,4-selective polymerization of (E,E)-methyl sorbate (MS) and (E-E)-ethyl sorbates (ES).
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Saccharin-pendant methacrylamide as a unique monomer in radical copolymerization: peculiar alternating copolymerization with styrene
Yuki Kametani,Makoto Ouchi +1 more
TL;DR: In this article, the authors reported an unusual reactivity of saccharin-pendant methacrylamide (1) in radical copolymerization, where the side chains of 1 were converted into methyl ester via hydrolysis and methylation.
References
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Journal ArticleDOI
Sequence-controlled polymers.
TL;DR: This work reviews the progress that has been made in making sequence-controlled polymers of increasing length and complexity and proposes some strategies for controlling sequences in chain-growth and step-growth polymerizations.
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From precision polymers to complex materials and systems
TL;DR: In this paper, the authors highlight that most of the necessary elements for the development of more complex synthetic matter are available today using modern strategies, such as controlled radical polymerizations, supramolecular polymerizations or stepwise synthesis, polymers with precisely controlled molecular structures can be synthesized.
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Sequence-controlled polymerizations: the next Holy Grail in polymer science?
TL;DR: In this paper, a short perspective article is presented to sensitize polymer chemists to the importance of controlling comonomer sequences, which is the key to functional sub-nanometric materials.
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Single-chain technology using discrete synthetic macromolecules
TL;DR: These recent advances in macromolecular science are described in detail and the possible emergence of technologies based on single-chain devices are emphasized.