Journal ArticleDOI
Valence rearrangement of hetero systems. The 4-isoxazolines
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This article is published in Journal of the American Chemical Society.The article was published on 1968-09-01. It has received 117 citations till now. The article focuses on the topics: Valence (chemistry).read more
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Intramolecular dipolar cycloaddition reactions of azomethine ylides.
Iain Coldham,Richard Hufton +1 more
TL;DR: This review aims to describe the background and mechanisms of azomethine ylide formation and intramolecular cycloaddition, giving a critical account including the very first example and covering to early 2005.
Journal ArticleDOI
Click Chemistry in Complex Mixtures: Bioorthogonal Bioconjugation
Craig S. McKay,M. G. Finn +1 more
TL;DR: An update on recent developments in bioorthogonal chemistry that highlights key advances in reaction rates, biocompatibility, and applications is provided.
Journal ArticleDOI
Catalytic Access to α-Oxo Gold Carbenes by N–O Bond Oxidants
Hyun-Suk Yeom,Seunghoon Shin +1 more
TL;DR: A variety of tandem reactions performed by the laboratory and others have demonstrated the synthetic utility of catalytically generated α-oxo gold carbenes and enabled access to various heterocycles.
Journal ArticleDOI
Recent Advances in Gold-Catalyzed N- and O-Functionalizations of Alkynes with Nitrones, Nitroso, Nitro and Nitroxy Species
TL;DR: In this article, a review summarizes recent progress to implement N-and O-functionalizations of alkynes with common NO containing species including nitrone, nitroso, and other nitroxy derivatives.
Book ChapterDOI
Recent Advances in Azomethine Ylide Chemistry
Otohiko Tsuge,Shuji Kanemasa +1 more
TL;DR: Azomethine ylides are planar molecules composed of one nitrogen and two terminal sp2 carbons at most four geometrical isomers are possible for these transient molecules Their cycloadditions to olefin or acetylene dipolarophiles give rise to the formation of two sets of carbon-carbon bonds in a single step as discussed by the authors.