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Journal ArticleDOI

Zerovalent transition metal complexes of organic isocyanides

Yasuhiro Yamamoto
- 01 Aug 1980 - 
- Vol. 32, Iss: 3, pp 193-233
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This article is published in Coordination Chemistry Reviews.The article was published on 1980-08-01. It has received 178 citations till now. The article focuses on the topics: Transition metal.

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Citations
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Journal ArticleDOI

Cobalt‐Mediated [2 + 2 + 2]‐Cycloadditions: A Maturing Synthetic Strategy [New Synthetic Methods (43)]

TL;DR: Dicarbonyl (η5-cyclopentadienyl)cobalt functions as a matrix on which a variety of unsaturated organic substrates undergo mutual bond formation as mentioned in this paper.
Book ChapterDOI

Metal Isocyanide Complexes

TL;DR: A number of reproducible synthetic routes to six-and seven-coordinate isocyanide complexes of molybdenum and tungsten have been developed over the years as mentioned in this paper.
Journal ArticleDOI

Cobalt-vermittelte [2+2+2]-Cycloadditionen: eine ausgereifte Synthesestrategie

TL;DR: In vielen Fallen verlaufen diese Reaktionen with bemerkenswerter Chemo-, Regio-and Stereoselektivitat, die zum Teil durch Trimethyl-silylsubstituenten als kontrollierende und dirigierenden Gruppen ermoglicht werden as mentioned in this paper.
Journal ArticleDOI

Palladium-Catalyzed Cascade Process Consisting of Isocyanide Insertion and Benzylic C(sp3)–H Activation: Concise Synthesis of Indole Derivatives

TL;DR: It was found that slow addition of isocyanide is effective for reducing the amount of catalyst needed and Ad(2)P(n)Bu is a good ligand for C(sp(3))-H activation.
References
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Journal ArticleDOI

Reactions of (π-1,5-cyclooctadiene) organoplatinum(II) compounds and the synthesis of perfluoroalkylplatinum complexes

TL;DR: An improved synthesis for the complexes PtR 2 (COD) is described in this article, where the coupling constant J(Pt-H) to the olefinic carbons varies with the trans influence of the trans-ligand.
Journal ArticleDOI

Cyclopentadienyl-carbon monoxide and related compounds of some transitional metals

TL;DR: In this paper, the preparation of cyclopentadienyl-carbon monoxide compounds of manganese, iron and cobalt is described, and the configurations and structures of the compounds are discussed briefly.