Journal ArticleDOI
Cyclopentadienyl-carbon monoxide and related compounds of some transitional metals
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In this paper, the preparation of cyclopentadienyl-carbon monoxide compounds of manganese, iron and cobalt is described, and the configurations and structures of the compounds are discussed briefly.Citations
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Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron
T.S. Piper,G. Wilkinson +1 more
TL;DR: In this article, the preparation of alkyl and aryl π-cyclopentadienyl carbon monoxide or nitric oxide compounds of Cr, Mo, W, and Fe is described.
Journal ArticleDOI
Organometallic chemistry of the transition metals XXI. Some π-pentamethylcyclopentadienyl derivatives of various transition metals
R.B. King,M.B. Bisnette +1 more
TL;DR: In this paper, it was shown that pentamethylcyclopentadiene itself reacts with hexacarbonylmolybdenum to give red-violet (CH 3 ) 5 C 5 Mo(CO) 3 ] − anion identified by conversion to the orange methyl derivative with methyl iodide.
Journal ArticleDOI
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.
TL;DR: The striking influence of coordinating NHSi's to transition-metal complex fragments affording different reactivities to the "free" NHSi is a connecting theme ("leitmotif") throughout the review, and highlights the potential of these compounds which lie at the interface of contemporary main-group and classical organometallic chemistry towards new molecular catalysts for small-molecule activation.
Book ChapterDOI
Compounds Derived from Alkynes and Carbonyl Complexes of Cobalt
R.S. Dickson,P.J. Fraser +1 more
TL;DR: In this article, the development of metal carbonyl chemistry is discussed and the rate of exchange of carbon monoxide with several other CO2(CO)6(RC2R´) complexes in hexane is investigated.
Journal ArticleDOI
On manganese cyclopentadienide and some chemical reactions of neutral bis-cyclopentadienyl metal compounds
TL;DR: The compound (C5H5)2Mn has been shown to be ionic in nature by magnetic studies and by other physical and chemical evidence as mentioned in this paper, and the reaction of the manganous halides with C5H 5Na in tetrahydrofuran solution has been described.
References
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Journal ArticleDOI
CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS
G. Wilkinson,J. M. Birmingham +1 more
Journal ArticleDOI
Bis-cyclopentadienyl Iron: a Molecular Sandwich
Jack D. Dunitz,L. E. Orgel +1 more
TL;DR: In this paper, the authors present X-ray evidence for the correctness of (II) and also interpret this unusual structure in terms of electronic structural principles, based on which they have proposed the very unorthodox structures (II or (III).
Journal ArticleDOI
Bis-cyclopentadienyl Compounds of Nickel and Cobalt
Related Papers (5)
Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron
T.S. Piper,G. Wilkinson +1 more