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Andrei V. Churakov

Researcher at Russian Academy of Sciences

Publications -  460
Citations -  5398

Andrei V. Churakov is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Crystal structure & Hydrogen bond. The author has an hindex of 30, co-authored 428 publications receiving 4483 citations. Previous affiliations of Andrei V. Churakov include University of Marburg & Florida State University.

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Journal ArticleDOI

The substitution of arene by alkenes in linear trinuclear palladium complex Pd3(NO)2(μ-CF3CO2)4(η2-C6H5CH3)2. X-ray structure of Pd3(NO)2(μ-CF3CO2)4(η2-CH2CHPh)2 and Pd4(μ-NO)2(μ-CF3CO2)4(η2-CH2CHPh)4

TL;DR: In this article, a replacement of η2-coordinated arene by various olefins has been found to result in complexes of different nuclearity, Pd3(NO)2(μ-CF3CO2)4(η 2-L)2 (L ǫ = Me3CCH CH2 (III), CH2CHPh (IV), Pd4 (μ-NO) 2(mcf3CO 2)4 (η2 -C6H5Me)2 ) with alkenes.
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Structural diversity of polynuclear MgxOy cores in magnesium phenoxide complexes.

TL;DR: A polymerization test demonstrated the ability of (II) to catalyse the ring-opening polymerization of ℇ-caprolactone without activation by alcohol and the BHT ligand demonstrates the terminal κO-coordination mode.
Journal ArticleDOI

Reaction of 2,8-Bis(o-hydroxyaryl)quinolines with Group 4 Metal Alkyls Resulting in Three Distinct Coordination Modes of the Tridentate Ligand. X-ray Structure of Complexes and Performance as Precursors in Ethylene Polymerization Catalysis

TL;DR: A series of bis(o-hydroxyphenyl)quinolines have been prepared, starting from 2,8-dibromoquinoline as discussed by the authors, which results in active polymerization catalysts when activated with MAO/borate cocatalysts on silica supports, resulting in polyethylene copolymers with very high molecular weights and multimodal MWDs.