基礎講座 電気泳動(Electrophoresis)

http://www.cdi-electrosorption.org/wp-content/uploads/2014/06/Porada-et-al.-2013-Review-on-the-Science-and-Technology-of-Water-Desalination-by-Capacitive-Deionization.pdf

Review on the science and technology of water desalination by capacitive deionization

Micromachining technology was used to prepare chemical analysis systems on glass chips (1 centimeter by 2 centimeters or larger) that utilize electroosmotic pumping to drive fluid flow and electrophoretic separation to distinguish sample components. Capillaries 1 to 10 centimeters long etched in the glass (cross section, 10 micrometers by 30 micrometers) allow for capillary electrophoresis-based separations of amino acids with up to 75,000 theoretical plates in about 15 seconds, and separations of about 600 plates can be effected within 4 seconds. Sample treatment steps within a manifold of intersecting capillaries were demonstrated for a simple sample dilution process. Manipulation of the applied voltages controlled the directions of fluid flow within the manifold. The principles demonstrated in this study can be used to develop a miniaturized system for sample handling and separation with no moving parts.

Micromachining a miniaturized capillary electrophoresis-based chemical analysis system on a chip

Capillarity and Wetting Phenomena: Drops, Bubbles, Pearls, Waves

Atmospheric water is a resource equivalent to ~10% of all fresh water in lakes on Earth. However, an efficient process for capturing and delivering water from air, especially at low humidity levels (down to 20%), has not been developed. We report the design and demonstration of a device based on a porous metal-organic framework {MOF-801, [Zr6O4(OH)4(fumarate)6]} that captures water from the atmosphere at ambient conditions by using low-grade heat from natural sunlight at a flux of less than 1 sun (1 kilowatt per square meter). This device is capable of harvesting 2.8 liters of water per kilogram of MOF daily at relative humidity levels as low as 20% and requires no additional input of energy.

https://science.sciencemag.org/content/sci/early/2017/04/12/science.aam8743.full.pdf

Water harvesting from air with metal-organic frameworks powered by natural sunlight

This paper presents a unique optical technique that utilizes the reabsorption and emission of two fluorescent dyes to accurately measure film thickness while minimizing errors caused by variations in illumination intensity and surface reflectivity. Combinations of dyes are selected that exhibit a high degree of emission reabsorption and each dye concentration is adjusted to create an optically thick system where emission reabsorption is intrinsic to the fluorescence of the film being measured. Film thickness information as well as excitation and dye response characteristics are all imbedded in the emission intensities of the dyes. Errors normally associated with laser induced fluorescence based film thickness measurements, including those due to optical distortion, variations in surface reflectivity and excitation non-uniformities, are minimized by observing the ratio of the dye emissions. The principle and constitutive equations characterizing emission reabsorption laser induced fluorescence (ERLIF) film thickness measurement are presented. In addition, film thickness measurements from 5 to 400 µm with 1% accuracy are demonstrated.

https://iopscience.iop.org/article/10.1088/0957-0233/12/4/310/pdf

Emission reabsorption laser induced fluorescence (ERLIF) film thickness measurement

3-D numerical simulation of contact angle hysteresis for microscale two phase flow

Energetic performance optimization of a capacitive deionization system operating with transient cycles and brackish water

We present a cost-efficient and rapid prototyping technique for polymethylmethacrylate (PMMA) microfluidic devices using a polydimethylsiloxane (PDMS)-based hot embossing process. Compared to conventional hot embossing methods, this technique uses PDMS molds with enhanced thermo-mechanical properties. To improve the replication performance, increases in both PDMS stiffness and hardness were achieved through several processing and curing means. First, the amount of curing agent was increased from 1/10 to 1/5 with respect to the amount of prepolymer. Second, the cured PDMS was thermally aged either over three days at 85 ◦ C or for 30 min at 250 ◦ C. Those combined steps led to increases in stiffness and hardness of up to 150% and 32%, respectively, as compared to standard PDMS molds. Using these enhanced molds, structures with features of the order of 100 μm in PMMA are successfully embossed using a standard laboratory press at 150 ◦ C. The PDMS molds and process produce identical structures through multiple embossing cycles (10) without any mold damage or deterioration. A Y-shaped microfluidic mixer was fabricated with this technique. The successful demonstration of this enhanced PDMS-based hot embossing technique introduces a new approach for the rapid prototyping of polymer-based microfluidic devices at low-cost. (Some figures may appear in colour only in the online journal)

https://iopscience.iop.org/article/10.1088/0960-1317/23/9/095024/pdf

Enhancement of the thermo-mechanical properties of PDMS molds for the hot embossing of PMMA microfluidic devices

Friction reduction in microchannel flows can help alleviate the inherently taxing pumping power requirements associated with the dimensions involved. One possible way of achieving friction reduction is through the introduction of surface microtexturing that can lead to a superhydrophobic Cassie-Baxter state. The Cassie-Baxter state is characterized by the presence of air pockets within the surface microtexturing believed to act as an effective “shear free” (or at least shear reduced) layer, decreasing the overall friction characteristics of the surface. Most work in this area has concentrated on optimizing the surface microtexturing geometry to maximize the friction reduction effects and overall stability of the Cassie-Baxter state. However, less attention has been paid to the effects of partially wetted conditions induced by pressure and the correlation between the liquid-gas interface location within the surface microtexturing and the microchannel flow characteristics. This is mainly attributed to the difficulty in tracking the interface shape and location within the microtexturing in the typical top-down view arrangements used in most studies. In this paper, a rectangular microchannel with regular microtexturing on the sidewalls is used to visualize and track the location of the air-water interface within the roughness elements. While visually tracking the wetting conditions in the microtextures, pressure drops versus flow rates for each microchannel are measured and analyzed in terms of the non-dimensional friction coefficient. The frictional behavior of the Poiseuille flow suggests that (1) the air-water interface more closely resembles a no-slip boundary rather than a shear-free one, (2) the friction is rather insensitive to the degree of microtexturing wetting, and (3) the fully wetted (Wenzel state) microtexturing provides lower friction than the non-wetted one (Cassie state), in corroboration with observations (1) and (2).

Carlos Hidrovo

Papers

Emission reabsorption laser induced fluorescence (ERLIF) film thickness measurement

3-D numerical simulation of contact angle hysteresis for microscale two phase flow

Energetic performance optimization of a capacitive deionization system operating with transient cycles and brackish water

Enhancement of the thermo-mechanical properties of PDMS molds for the hot embossing of PMMA microfluidic devices

Pressure and partial wetting effects on superhydrophobic friction reduction in microchannel flow