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Carsten Jenne
Researcher at University of Wuppertal
Publications - 44
Citations - 754
Carsten Jenne is an academic researcher from University of Wuppertal. The author has contributed to research in topics: Crystal structure & Radical. The author has an hindex of 14, co-authored 43 publications receiving 593 citations.
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Journal ArticleDOI
Silver-Free Activation of Ligated Gold(I) Chlorides: The Use of [Me3NB12Cl11]− as a Weakly Coordinating Anion in Homogeneous Gold Catalysis
TL;DR: Phosphane and N-heterocyclic carbene ligated gold(I) chlorides can be effectively activated by Na[Me3NB12Cl11] (1) under silver-free conditions and the capability of 1 in a previously unknown conversion of 5-silyloxy-1,6-allenynes was demonstrated.
Journal ArticleDOI
On the Oxidation of the Three‐Dimensional Aromatics [B12X12]2− (X=F, Cl, Br, I)
René T. Boeré,Janis Derendorf,Carsten Jenne,Sylwia Kacprzak,Mathias Keßler,Rainer Riebau,Sebastian Riedel,Tracey L. Roemmele,Monika Rühle,Harald Scherer,Thomas Vent-Schmidt,Jonas Warneke,Stefan Weber +12 more
TL;DR: The perhalogenated closo-dodecaborate dianions [B12 X12 ](2-) are three-dimensional counterparts to the two-dimensional aromatics C6 X6 and showed a complex oxidation behavior in cyclic voltammetry experiments, presumably owing to decomposition of the cluster anion under release of iodide, which also explains the failure to isolate the respective radical by chemical oxidation.
Journal ArticleDOI
Synthesis and Properties of the Weakly Coordinating Anion [Me3NB12Cl11]−
Christoph Bolli,Janis Derendorf,Carsten Jenne,Harald Scherer,Christian P. Sindlinger,Bianca Wegener +5 more
TL;DR: The facile preparation of the [Me3 NB12 Cl11 ](-) anion and its ideal chemical and physical properties make it a cheap alternative to other classes of weakly coordinating anions.
Journal ArticleDOI
Rational design of an argon-binding superelectrophilic anion
Martin Mayer,Valentin van Lessen,Markus Rohdenburg,Gao-Lei Hou,Zheng Yang,Rüdiger M. Exner,Edoardo Aprà,Vladimir A. Azov,Simon Grabowsky,Sotiris S. Xantheas,Sotiris S. Xantheas,Knut R. Asmis,Xue-Bin Wang,Carsten Jenne,Jonas Warneke,Jonas Warneke +15 more
TL;DR: A concept for the rational design of anionic superelectrophiles that are composed of a strong electrophilic center firmly embedded in a negatively charged framework of exceptional stability is reported.
Journal ArticleDOI
Electronic Structure and Stability of [B12X12]2- (X = F-At): A Combined Photoelectron Spectroscopic and Theoretical Study.
Jonas Warneke,Gao-Lei Hou,Edoardo Aprà,Carsten Jenne,Zheng Yang,Zhengbo Qin,Karol Kowalski,Xue-Bin Wang,Sotiris S. Xantheas,Sotiris S. Xantheas +9 more
TL;DR: The unusual intrinsic electronic structure of the [B12X12]2- MCAs provides the basis for a molecular level understanding of their observed unique physical and chemical properties and a new paradigm for understanding the properties of these MCAs with not well-separated charges that departs from the prevailing model used for spatially separated charges.