Gao-Lei Hou

TL;DR: A concept for the rational design of anionic superelectrophiles that are composed of a strong electrophilic center firmly embedded in a negatively charged framework of exceptional stability is reported.

TL;DR: The unusual intrinsic electronic structure of the [B12X12]2- MCAs provides the basis for a molecular level understanding of their observed unique physical and chemical properties and a new paradigm for understanding the properties of these MCAs with not well-separated charges that departs from the prevailing model used for spatially separated charges.

TL;DR: This work provides direct experimental evidence showing significant thermodynamic advantage by involving organic acid molecules to promote formation and growth in bisulfate clusters and aerosols.

TL;DR: The electronic emission characteristics of 13 gas-phase PAHs were investigated to diagnose laser-induced fluorescence (LIF) spectra ofPAHs in flame by DFT, TD-DFT, and premixed flame modeling methods and it was found that naphthalene should be responsible for the fluorescence located in the 312-340 nm region in the flame.

TL;DR: In this article, three newly synthesized [Na+(221-Kryptofix)] salts containing AsCO, PCO, and PCS were successfully electrosprayed into a vacuum, and these three ECX-anions were investigated by negative ion photoelectron spectroscopy (NIPES) along with high-resolution photo-electron imaging spectroscopic.