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Carsten Jenne
Researcher at University of Wuppertal
Publications - 44
Citations - 754
Carsten Jenne is an academic researcher from University of Wuppertal. The author has contributed to research in topics: Crystal structure & Radical. The author has an hindex of 14, co-authored 43 publications receiving 593 citations.
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Journal ArticleDOI
Direct functionalization of C-H bonds by electrophilic anions
Jonas Warneke,Jonas Warneke,Jonas Warneke,Martin Mayer,Markus Rohdenburg,Xin Ma,Judy Liu,Max Grellmann,Sreekanta Debnath,Vladimir A. Azov,Edoardo Aprà,Robert P. Young,Carsten Jenne,Grant E. Johnson,Hilkka I. Kenttämaa,Knut R. Asmis,Julia Laskin +16 more
TL;DR: A new mechanism of alkane functionalization by the substitution of a proton by an anion in an alkyl chain is demonstrated, paving the way for exploiting the properties of gaseous ions for the generation of complex molecular structures in the condensed phase.
Journal ArticleDOI
Theoretical and Synthetic Study on the Existence, Structures, and Bonding of the Halide-Bridged [B2X7]− (X = F, Cl, Br, I) Anions
Philipp Bertocco,Christoph Bolli,Bruno A. Correia Bicho,Carsten Jenne,Berrin Erken,Risto S. Laitinen,Helene Seeger,Teemu T. Takaluoma,Teemu T. Takaluoma +8 more
TL;DR: The thermodynamic stability of the [B2X7](-) anions was estimated in all phases (gas, solution, and solid state) based on quantum-chemical calculations and estimations of the lattice enthalpies using a volume-based approach.
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Anion–Anion Chemistry with Mass-Selected Molecular Fragments on Surfaces
Fangshun Yang,K. Antonio Behrend,Harald Knorke,Markus Rohdenburg,Ales Charvat,Carsten Jenne,Bernd Abel,Jonas Warneke +7 more
TL;DR: In this article, it was shown that reactions between fragment ions generated in the gas phase and molecular ions of the same polarity are possible by soft-landing of both reagents on surfaces.
Journal ArticleDOI
Properties of gaseous closo-[B6X6]2− dianions (X = Cl, Br, I)
Markus Rohdenburg,Zheng Yang,Pei Su,Eduard Bernhardt,Qinqin Yuan,Edoardo Aprà,Simon Grabowsky,Julia Laskin,Carsten Jenne,Xue-Bin Wang,Jonas Warneke,Jonas Warneke +11 more
TL;DR: The calculated reaction enthalpies of the three competing dissociation pathways indicated a strong influence of kinetic factors on the observed fragmentation patterns and a significantly lower RCB for X- loss than for e- loss was found in both experimental and theoretical investigations and can be rationalized by the recently introduced concept of electrophilic anions.
Journal ArticleDOI
Relevance of π-Backbonding for the Reactivity of Electrophilic Anions [B12X11]− (X=F, Cl, Br, I, CN)
Martin Mayer,Markus Rohdenburg,Markus Rohdenburg,Sebastian Kawa,Francine Horn,Harald Knorke,Carsten Jenne,Ralf Tonner,Knut R. Asmis,Jonas Warneke,Jonas Warneke +10 more
TL;DR: In this article, the reactivity of closo-borate anions of type [B12 X11 ]- with X=F, Cl, Br, I, CN is characterized towards different nucleophiles: noble gases (NGs) as σ-donors and CO/N2 asπ-acceptors.