Daniel Raftery

TL;DR: Although currently overshadowed by MS in terms of numbers of compounds resolved, NMR spectroscopy offers advantages both on its own and coupled with MS, and is adept at tracing metabolic pathways and fluxes using isotope labels.

TL;DR: The current trends and recent advances in NMR- and MS-based metabolomics are described with a focus on the development of advanced NMR and MS methods, improved multivariate statistical data analysis and recent applications in the area of cancer, diabetes, inborn errors of metabolism and cardiovascular diseases.

TL;DR: This review will highlight a number of emerging NMR techniques and technologies that are being used to strengthen its utility and overcome its inherent limitations in metabolomic applications.

TL;DR: In this paper, a vanadium-doped, supported TiO2 photocatalyst is presented which is quite active using visible (396−450 nm) light, and the oxidation of ethanol over this catalyst was studied using 13C solid-state NMR methods that demonstrated that this catalyst photooxidizes ethanol to produce mostly carbon dioxide with small amounts of acetaldehyde, formic acid, and carbon monoxide under visible irradiation.