D
Debasish Mandal
Researcher at Thapar University
Publications - 80
Citations - 2121
Debasish Mandal is an academic researcher from Thapar University. The author has contributed to research in topics: Chemistry & Medicine. The author has an hindex of 22, co-authored 59 publications receiving 1537 citations. Previous affiliations of Debasish Mandal include Indian Association for the Cultivation of Science & Indian Institute of Toxicology Research.
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Oriented electric fields as future smart reagents in chemistry
TL;DR: It is postulate that, as experimental techniques mature, chemical syntheses may become an exercise in zapping oriented molecules with OEEFs, and the wide-ranging potential of using OEEF to catalyse and control a variety of non-redox reactions and impart selectivity at will is discussed.
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Structure and reactivity/selectivity control by oriented-external electric fields
TL;DR: The tutorial instructs readers how to conceptualize and design electric-field effects on bonds, structures, and reactions, and projects the unity of EEF effects, "giving insight and numbers".
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How Does Tunneling Contribute to Counterintuitive H-Abstraction Reactivity of Nonheme Fe(IV)O Oxidants with Alkanes?
TL;DR: The present results corroborate the initially predicted two-state reactivity (TSR) scenario for these reactions and support the "tunneling control" hypothesis.
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Interplay of Experiment and Theory in Elucidating Mechanisms of Oxidation Reactions by a Nonheme RuIVO Complex
Sunder N. Dhuri,Sunder N. Dhuri,Kyung Bin Cho,Yong Min Lee,Sun Young Shin,Jin Hwa Kim,Debasish Mandal,Sason Shaik,Wonwoo Nam +8 more
TL;DR: In alkane hydroxylation and the oxidation of olefins by 1, the observations of a kinetic isotope effect (KIE) value of 1 and styrene oxide formation lead us to conclude that an epoxidation reaction via oxygen atom transfer (OAT) from the Ru(IV)O complex to the C═C double bond is the dominant pathway.
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Highly sensitive and selective rhodamine-based "off-on" reversible chemosensor for tin (Sn4+) and imaging in living cells.
TL;DR: A structurally characterized new oxo-chromene functionalized rhodamine derivative L1 exhibits high selectivity toward Sn(4+) by forming a 1:1 complex, among other biologically important metal ions, as studied by fluorescence, absorption, and HRMS spectroscopy.