E
Eberhardt Herdtweck
Researcher at Technische Universität München
Publications - 332
Citations - 11434
Eberhardt Herdtweck is an academic researcher from Technische Universität München. The author has contributed to research in topics: Catalysis & Carbene. The author has an hindex of 56, co-authored 332 publications receiving 10785 citations. Previous affiliations of Eberhardt Herdtweck include Jordan University of Science and Technology & Ludwig Maximilian University of Munich.
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Journal ArticleDOI
Structure−Reactivity Relationships in Rare-Earth Metal Carboxylate-Based Binary Ziegler-Type Catalysts
TL;DR: In this article, the organoaluminum-mediated alkylation of tailor-made rare-earth metal carboxylate complexes was investigated, and implications of the degree of Ln-chloride-mediated cation formation for 1,3-diene polymerization were investigated.
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Chiral N-Heterocyclic Carbene Ligands Derived from 2,2‘-Bipiperidine and Partially Reduced Biisoquinoline: Rhodium and Iridium Complexes in Asymmetric Catalysis†
Wolfgang A. Herrmann,Denys Baskakov,Eberhardt Herdtweck,Stephan D. Hoffmann,Tanasri Bunlaksananusorn,Florian Rampf,Lars Rodefeld +6 more
TL;DR: In this paper, a procedure for the preparation of chiral N-heterocyclic carbenes from 2,2'bipiperidine and partially reduced biisoquinoline was developed.
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Chiral N-Heterocyclic Carbenes with Restricted Flexibility in Asymmetric Catalysis†
TL;DR: In this paper, a chiral C2-symmetric diamine was prepared from (S)-3-phenyl-3,4-dihydroisoquinoline by the virtue of asymmetric transformation Rhodium and iridium complexes of chiral N-heterocyclic carbenes with restricted flexibility derived from 3,3'substituted partially reduced bi isoquinoline were obtained by transmetalation from the corresponding silver(I) complexes.
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An efficient protocol for the palladium-catalysed Suzuki–Miyaura cross-coupling
Alexander N. Marziale,Dominik Jantke,Stefan H. Faul,Thomas Reiner,Eberhardt Herdtweck,Jörg Eppinger +5 more
TL;DR: In this article, an efficient, broadly applicable and sustainable aqueous protocol was developed using 2.5 eq. of Na2CO3 as base, allowing the reaction to be performed under air and at ambient temperature with Pd loadings of 0.04 mol%.
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Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation
Walter Baratta,Giorgio Chelucci,Eberhardt Herdtweck,Santo Magnolia,Katia Siega,Pierluigi Rigo +5 more
TL;DR: Ruthenium cis -dichloro complexes with matched chiral diphosphane and aminopyridine ligands are highly active catalysts for the transfer hydrogenation of ketones, affording turnover frequencies of up to 70 000 h -1 at 60 ° C and ee values up to 99 %.