We present a new model for computing the spectral evolution of stellar populations at ages between 100,000 yr and 20 Gyr at a resolution of 3 A across the whole wavelength range from 3200 to 9500 A for a wide range of metallicities. These predictions are based on a newly available library of observed stellar spectra. We also compute the spectral evolution across a larger wavelength range, from 91 A to 160 micron, at lower resolution. The model incorporates recent progress in stellar evolution theory and an observationally motivated prescription for thermally-pulsing stars on the asymptotic giant branch. The latter is supported by observations of surface brightness fluctuations in nearby stellar populations. We show that this model reproduces well the observed optical and near-infrared colour-magnitude diagrams of Galactic star clusters of various ages and metallicities. Stochastic fluctuations in the numbers of stars in different evolutionary phases can account for the full range of observed integrated colours of star clusters in the Magellanic Clouds. The model reproduces in detail typical galaxy spectra from the Early Data Release (EDR) of the Sloan Digital Sky Survey (SDSS). We exemplify how this type of spectral fit can constrain physical parameters such as the star formation history, metallicity and dust content of galaxies. Our model is the first to enable accurate studies of absorption-line strengths in galaxies containing stars over the full range of ages. Using the highest-quality spectra of the SDSS EDR, we show that this model can reproduce simultaneously the observed strengths of those Lick indices that do not depend strongly on element abundance ratios [abridged].

https://hal.archives-ouvertes.fr/hal-00012948/document

Stellar population synthesis at the resolution of 2003

This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity. Moreover, molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth. Of considerable note, experimental IR cross-sections for almost 300 additional molecules important in different areas of atmospheric science have been added to the database. The compilation can be accessed through www.hitran.org. Most of the HITRAN data have now been cast into an underlying relational database structure that offers many advantages over the long-standing sequential text-based structure. The new structure empowers the user in many ways. It enables the incorporation of an extended set of fundamental parameters per transition, sophisticated line-shape formalisms, easy user-defined output formats, and very convenient searching, filtering, and plotting of data. A powerful application programming interface making use of structured query language (SQL) features for higher-level applications of HITRAN is also provided.

/pdf/the-hitran-2008-molecular-spectroscopic-database-1ud8clpej3.pdf

The HITRAN 2008 molecular spectroscopic database

We review progress over the past decade in observations of large-scale star formation, with a focus on the interface between extragalactic and Galactic studies. Methods of measuring gas contents and star-formation rates are discussed, and updated prescriptions for calculating star-formation rates are provided. We review relations between star formation and gas on scales ranging from entire galaxies to individual molecular clouds.

Star Formation in the Milky Way and Nearby Galaxies

IR emission spectra are calculated for dust heated by starlight, for mixtures of amorphous silicate and graphitic grains, including varying amounts of PAH particles. The models are constrained to reproduce the average Milky Way extinction curve. The calculations include the effects of single-photon heating. Updated IR absorption properties for the PAHs are presented that are consistent with observed emission spectra, including those newly obtained by Spitzer. We find a size distribution for the PAHs giving emission band ratios consistent with the observed spectra of the Milky Way and other galaxies. Emission spectra are presented for a wide range of starlight intensities. We calculate how the efficiency of emission into different IR bands depends on PAH size; the strong 7.7 μm emission feature is produced mainly by PAH particles containing Umin. We present graphical procedures using Spitzer IRAC and MIPS photometry to estimate the parameters qPAH, Umin, and γ, the fraction fPDR of the dust luminosity coming from photodissociation regions with U > 100, and the total dust mass Mdust.

https://iopscience.iop.org/article/10.1086/511055/pdf

Infrared Emission from Interstellar Dust. IV. The Silicate-Graphite-PAH Model in the Post-Spitzer Era

: The unpolarized absorption and circular dichroism spectra of the fundamental vibrational transitions of the chiral molecule, 4-methyl-2-oxetanone, are calculated ab initio. Harmonic force fields are obtained using Density Functional Theory (DFT), MP2, and SCF methodologies and a 5S4P2D/3S2P (TZ2P) basis set. DFT calculations use the Local Spin Density Approximation (LSDA), BLYP, and Becke3LYP (B3LYP) density functionals. Mid-IR spectra predicted using LSDA, BLYP, and B3LYP force fields are of significantly different quality, the B3LYP force field yielding spectra in clearly superior, and overall excellent, agreement with experiment. The MP2 force field yields spectra in slightly worse agreement with experiment than the B3LYP force field. The SCF force field yields spectra in poor agreement with experiment.The basis set dependence of B3LYP force fields is also explored: the 6-31G* and TZ2P basis sets give very similar results while the 3-21G basis set yields spectra in substantially worse agreements with experiment. jg

Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields

In recent decades, a number of molecules and diverse dust features have been identified by astronomical observations in various environments. Most of the dust that determines the physical and chemical characteristics of the interstellar medium is formed in the outflows of asymptotic giant branch stars and is further processed when these objects become planetary nebulae. We studied the environment of Tc 1, a peculiar planetary nebula whose infrared spectrum shows emission from cold and neutral C60 and C70. The two molecules amount to a few percent of the available cosmic carbon in this region. This finding indicates that if the conditions are right, fullerenes can and do form efficiently in space.

https://science.sciencemag.org/content/sci/329/5996/1180.full.pdf

Detection of C60 and C70 in a Young Planetary Nebula

IR spectroscopy provides a valuable tool for the characterisation and identification of interstellar molecular species. Here, we present 6-9 mum spectra of a sample of reflection nebulae, HII regions, YSOs, evolved stars and galaxies that show strong unidentified infrared bands, obtained with the SWS spectrograph on board ISO. The IR emission features in this wavelength region show pronounced variations. 1) The 6.2 mum feature shifts from 6.22 to 6.3 mum and clearly shows profile variations. 2) The 7.7 mum complex is comprised of at least two subpeaks peaking at 7.6 and one longwards of 7.7 mum. In some cases the main peak can apparently shift up to 8 mum. Two sources do not exhibit a 7.7 mum complex but instead show a broad emission feature at 8.22 mum. 3) The 8.6 mum feature has a symmetric profile in all sources and some sources exhibit this band at slightly longer wavelengths. For the 6.2, 7.7 and 8.6 mum features, the sources have been classified independently based on their profile and peak position. The classes derived for these features are directly linked with each other. Sources with a 6.2 mum feature peaking at similar to6.22 mum exhibit a 7.7 mum complex dominated by the 7.6 mum component. In contrast, sources with a 6.2 mum profile peaking longwards of 6.24 mum show a 7.7 mum complex with a dominant peak longwards of 7.7 mum and a 8.6 mum feature shifted toward the red. Furthermore, the observed 6-9 mum spectrum depends on the type of object. All ISM-like sources and a few PNe and Post-AGB stars belong to the first group while isolated Herbig AeBe stars, a few Post-AGB stars and most PNe belong to the second group. We summarise existing laboratory data and theoretical quantum chemical calculations of the modes emitting in this wavelength region of PAH molecules. We discuss the variations in peak position and profile in view of the exact nature of the carrier. We attribute the observed 6.2 mum profile and peak position to the combined effect of a PAH family and anharmonicity with pure PAHs representing the 6.3 mum component and substituted/complexed PAHs representing the 6.2 mum component. The 7.6 mum component is well reproduced by both pure and substituted/complexed PAHs but the 7.8 mum component remains an enigma. In addition, the exact identification of the 8.22 mum feature remains unknown. The observed variations in the characteristics of the IR emission bands are linked to the local physical conditions. Possible formation and evolution processes that may influence the interstellar PAH class are highlighted.

/pdf/the-rich-6-to-9-vec-mu-m-spectrum-of-interstellar-pahs-3yhw3a37kl.pdf

The rich 6 to 9 vec mu m spectrum of interstellar PAHs

Here, we present 6-9 um spectra of a sample of RNe, HII regions, YSOs, evolved stars and galaxies that show strong unidentified infrared bands, obtained with the ISO-SWS. The IR emission features show pronounced variations. 1) The 6.2 um feature shifts and clearly shows profile variations. 2) The 7.7 um complex is comprised of at least two subpeaks peaking at 7.6 and one longwards of 7.7 um. In some cases the main peak can apparently shift up to 8 um. Two sources do not exhibit a 7.7 um complex but instead show a broad emission feature at 8.22 um. 3) The 8.6 um feature has a symmetric profile in all sources and some sources exhibit this band at slightly longer wavelengths. For the 6.2, 7.7 and 8.6 um features, the sources have been classified independently based on their profile and peak position. The classes derived for these features are directly linked with each other. Furthermore, the observed 6--9 um spectrum depends on the type of object. We attribute the observed 6.2 um profile and peak position to the combined effect of a PAH family and anharmonicity with pure PAHs representing the 6.3 um component and substituted/complexed PAHs representing the 6.2 um component. The 7.6 um component is well reproduced by both pure and substituted/complexed PAHs but the 7.8 um component remains an enigma. In addition, the exact identification of the 8.22 um feature remains unknown. The observed variations in the characteristics of the IR emission bands are linked to the local physical conditions. Possible formation and evolution processes that may influence the interstellar PAH class are highlighted.

/pdf/the-rich-6-to-9-um-spectrum-of-interstellar-pahs-782yaqnfav.pdf

The rich 6 to 9 um spectrum of interstellar PAHs

Infrared (IR) emission features at 3.3, 6.2, 7.7, 8.6, and 11.3 ?m are generally attributed to IR fluorescence from (mainly) far-ultraviolet (FUV) pumped large polycyclic aromatic hydrocarbon (PAH) molecules. As such, these features trace the FUV stellar flux and are thus a measure of star formation. We examined the IR spectral characteristics of Galactic massive star-forming regions and of normal and starburst galaxies, as well as active galactic nuclei (AGNs) and ultraluminous infrared galaxies (ULIRGs). The goal of this study is to analyze whether PAH features are a good qualitative and/or quantitative tracer of star formation, and hence to evaluate the application of PAH emission as a diagnostic tool in order to identify the dominant processes contributing to the infrared emission from Seyfert galaxies and ULIRGs. We develop a new mid-infrared (MIR)/far-infrared (FIR) diagnostic diagram based on our Galactic sample and compare it to the diagnostic tools of Genzel and coworkers and Laurent and coworkers, with these diagnostic tools also applied to our Galactic sample. This MIR/FIR diagnostic is derived from the FIR normalized 6.2 ?m PAH flux and the FIR normalized 6.2 ?m continuum flux. Within this diagram, the Galactic sources form a sequence spanning a range of 3 orders of magnitude in these ratios, ranging from embedded compact H II regions to exposed photodissociation regions (PDRs) and the (diffuse) interstellar medium (ISM). However, the variation in the 6.2 ?m PAH feature-to-continuum ratio is relative small. Comparison of our extragalactic sample with our Galactic sources revealed an excellent resemblance of normal and starburst galaxies to exposed PDRs. While Seyfert 2 galaxies coincide with the starburst trend, Seyfert 1 galaxies are displaced by at least a factor of 10 in 6.2 ?m continuum flux, in accordance with general orientation-dependent unification schemes for AGNs. ULIRGs show a diverse spectral appearance. Some show a typical AGN hot dust continuum. More, however, either are starburst-like or show signs of strong dust obscuration in the nucleus. One characteristic of the ULIRGs also seems to be the presence of more prominent FIR emission than either starburst galaxies or AGNs. We discuss the observed variation in the Galactic sample in view of the evolutionary state and the PAH/dust abundance and discuss the use of PAHs as quantitative tracers of star formation activity. Based on these investigations, we find that PAHs may be better suited as a tracer of B stars, which dominate the Galactic stellar energy budget, than as a tracer of massive star formation (O stars).

https://iopscience.iop.org/article/10.1086/423237/pdf

Polycyclic aromatic hydrocarbons as a tracer of star formation

IR emission bands at 3.3, 6.2, 7.7, 8.6 and 11.3 um are generally attributed to IR fluorescence from (mainly) FUV pumped PAHs. As such, they trace the FUV stellar flux and are a measure of star formation. We examined the IR spectral characteristics of Galactic star forming regions, normal and starburst galaxies, AGNs and ULIRGs. The goal is to analyze if PAH bands are a good qualitative and/or quantitative tracer of star formation and hence the application of PAH bands as a diagnostic in order to identify the dominant processes contributing to the IR emission from Seyfert's and ULIRGs. We develop a MIR/FIR diagnostic and compare it to known diagnostics, with these also applied to the Galactic sample. This diagnostic is based on the FIR normalized 6.2 um PAH flux and the FIR normalized 6.2 um continuum flux. The Galactic sources form a sequence spanning a range of 3 orders of magnitude, from embedded compact HII regions to exposed PDRs and the (D)ISM. The variation in the 6.2 um PAH/continuum ratio is relative small. Normal and starburst galaxies ressemble exposed PDRs. While Seyfert-2's coincide with the starburst trend, Seyfert-1's are displaced by at least a factor 10 in 6.2 um continuum flux. ULIRGs show a diverse spectral appearance (AGN hot dust continuum, starburst-like or strong dust obscuration in the nucleus). ULIRGs also seems to have more prominent FIR emission than either starburst galaxies or AGNs. We discuss the observed variation in the Galactic sample in view of the evolutionary state and the PAH/dust abundance and the use of PAHs as quantitative tracers of star formation activity. We find that PAHs may be better suited as a tracer of B stars, which dominate the Galactic stellar energy budget, than as a tracer of massive star formation (O stars).

Els Peeters

Papers

Detection of C60 and C70 in a Young Planetary Nebula

The rich 6 to 9 vec mu m spectrum of interstellar PAHs

The rich 6 to 9 um spectrum of interstellar PAHs

Polycyclic aromatic hydrocarbons as a tracer of star formation

PAHs as a tracer of star formation