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Guillermo Mínguez Espallargas

Researcher at University of Valencia

Publications -  89
Citations -  6758

Guillermo Mínguez Espallargas is an academic researcher from University of Valencia. The author has contributed to research in topics: Coordination polymer & Halogen bond. The author has an hindex of 31, co-authored 80 publications receiving 5837 citations. Previous affiliations of Guillermo Mínguez Espallargas include Strathclyde Institute of Pharmacy and Biomedical Sciences & University of Sheffield.

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A SIM‐MOF: Three‐Dimensional Organisation of Single‐Ion Magnets with Anion‐Exchange Capabilities

TL;DR: A rational design of a family of MOFs, [Ln(bipyNO)4](TfO)3⋅x solvent (Ln=Tb (1); Dy (2); Ho (3); Er (4); TfO=triflate), in which the lanthanoid centres have an square-antiprismatic coordination environment suitable for SIM behaviour.
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A family of layered chiral porous magnets exhibiting tunable ordering temperatures.

TL;DR: The structural and magnetic characterization of this new family of anilato-based molecular magnets, formed by the association of a hydronium ion with three phenazine molecules, leads to a very unusual localization of both kinds of metals and to an eclipsed disposition of the layers.
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Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption

TL;DR: It is shown that the chemisorption of gaseous HCl molecules by a non-porous one-dimensional coordination polymer instigates drastic modifications in the magnetic properties of the material.
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Involving metals in halogen–halogen interactions: second-sphere Lewis acid ligands for perhalometallate ions (M–X⋯X′–C)

TL;DR: In this paper, the second-sphere ligands for perhalometallate ions were shown to provide an alternative means to hydrogen bonds for developing the supramolecular chemistry of such ions, exemplified by short directional M −X⋯X′−C halogen bond linkages used in conjunction with hydrogen bonds.