H
Hideki Yorimitsu
Researcher at Kyoto University
Publications - 624
Citations - 13349
Hideki Yorimitsu is an academic researcher from Kyoto University. The author has contributed to research in topics: Catalysis & Aryl. The author has an hindex of 57, co-authored 599 publications receiving 11722 citations. Previous affiliations of Hideki Yorimitsu include Tohoku University & University of Tokyo.
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Cobalt-catalyzed Heck-type reaction of alkyl halides with styrenes.
TL;DR: A cobalt complex, CoCl2[1,6-bis(diphenylphosphino)hexane], catalyzes an alkylation reaction of styrenes in the presence of Me3SiCH2MgCl in ether to yield beta-alkylstyrenes.
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Nickel-catalyzed carboxylation of organozinc reagents with CO2.
TL;DR: An efficient nickel catalyst system for the carboxylation of organozinc reagents with CO(2) under very mild conditions has been developed and enables the direct synthesis of various saturated carboxylic acid derivatives from the corresponding alkylzinc reagent reagents andCO(2).
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Powerful solvent effect of water in radical reaction: Triethylborane-induced atom-transfer radical cyclization in water
Hideki Yorimitsu,Tomoaki Nakamura,Hiroshi Shinokubo,Koichiro Oshima,Kiyoyuki Omoto,Hiroshi Fujimoto +5 more
TL;DR: In this paper, a triethylborane-induced atom-transfer radical cyclization of allyl iodoacetate (3a) is described and the remarkable solvent effect of water was observed in this reaction.
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Cobalt-Catalyzed Trimethylsilylmethylmagnesium-Promoted Radical Alkenylation of Alkyl Halides: A Complement to the Heck Reaction
Walter Affo,Hirohisa Ohmiya,Takuma Fujioka,Yousuke Ikeda,Tomoaki Nakamura,Hideki Yorimitsu,Koichiro Oshima,Yuki Imamura,Tsutomu Mizuta,Katsuhiko Miyoshi +9 more
TL;DR: Crystallographic and spectroscopic investigations on cobalt complexes reveal that the reaction would begin with single electron transfer from an electron-rich (diphosphine)bis(trimethylsilylmethyl)cobalt(II) complex followed by reductive elimination to yield 1,2-bis(diphenylphosphino)ethane and a (d PH2) complex.