H
Hiroaki Sasai
Researcher at Osaka University
Publications - 293
Citations - 9623
Hiroaki Sasai is an academic researcher from Osaka University. The author has contributed to research in topics: Enantioselective synthesis & Catalysis. The author has an hindex of 50, co-authored 278 publications receiving 9019 citations. Previous affiliations of Hiroaki Sasai include University of Burgundy & University of Tokyo.
Papers
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The First Heterobimetallic Multifunctional Asymmetric Catalyst.
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Direct Catalytic Asymmetric Aldol Reaction
TL;DR: In this article, the direct catalytic asymmetric aldol reaction using aldehydes and unmodified ketones is described for the first time, and a new heteropolymetallic asymmetric catalyst is developed.
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Development of the First Spiro Bis (isoxazoline) Ligands (SPRIXs) and Their Applications to Catalytic Enantioselective Reactions
TL;DR: The first chiral isoxazoline ligands bearing spiro skeleton were developed in this paper, which are readily synthesized from diethyl malonate via double intramolecular nitrile oxide cycloaddition as a key step.
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Chiral Vanadium(V)-catalyzed Oxidative Coupling of 4-Hydroxycarbazoles
Ganesh Tatya Kamble,Mohamed S. H. Salem,Mohamed S. H. Salem,Tsukasa Abe,Hanseok Park,Makoto Sako,Shinobu Takizawa,Hiroaki Sasai +7 more
TL;DR: In this article, a chiral dinuclear vanadium(V) complex was used for the first time to achieve anti-selective oxidative couplings of 4-hydroxy carbazoles.
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PdII/PdIV Catalytic Enantioselective Synthesis of Bicyclo[3.1.0]hexanes via Oxidative Cyclization of Enynes.
TL;DR: The first asymmetric PdII/PdIV catalysis was achieved by employing the combination of a hypervalent iodine reagent and a chiral ligand, SPRIX.