Hongyan Xiao

TL;DR: The multiple interactions and intermolecular charge transfer in the dimer structures are of significance in promoting the production of dimer triplet excited states and suppressing the nonradiative decays to boost the RTP under visible- and NIR-light irradiation in water.

TL;DR: It is demonstrated that the visible light–induced reaction NO3 → NO + O2 proceeds exclusively by roaming, and high-level ab initio calculations predict specific NO Λ doublet propensities for this mechanism, which is discerned experimentally by ion imaging.

TL;DR: The theoretical results do not support the experimentally deduced conclusion that the color modulation of the emitted light primarily depends on the size of the compact luciferase protein cavity embedding the excited oxyluciferin molecule, but it is found that the wavelength of the emission depends onThe polarity of the microenvironment at the phenol/phenolate terminal of the benzothiazole fragment in oxylUCiferin.

TL;DR: This work reports a general and simple method to realize the intermolecular dimerization reaction of these acyclic olefins to construct cyclobutanes in a highly regio- and diastereoselective manner in solution under visible light, which provides an efficient solution to a long-standing problem.

TL;DR: In this article, three donor-modified push-pull chromophores with the same divinylenethiophenyl bridge and tricyanofuran acceptor were synthesized, but with different modified donor moieties.