Jana K. Maclaren

TL;DR: In this paper, the authors used a manipulation experiment in which sodium hydroxide was added to seawater flowing over a natural coral reef community in situ and showed that when ocean chemistry was restored closer to pre-industrial conditions, net community calcification increased, indicating that ocean acidification may already be impairing coral reef growth.

TL;DR: The achiral chelating and bridging mesoxalato ligand (H2mesox2−), the conjugate base of dihydroxymalonic acid (H4mesox), is a new enantiopurity enforcer in extended structures by yielding the Λ/Δ-metal configured homochiral MOFs 2D-[Ln2(μ-H2 mesox)3(H2O)6], [with Ln(III) = La (1), Ce (2), Pr (3), Nd

TL;DR: A total synthesis of bryostatin 1 that proceeds in 29 total steps, collectively produces grams of material, and can be scaled to meet clinical needs (~20 grams per year), opens broad, facile, and efficient access to derivatives and potentially superior analogs.

TL;DR: Silver(I) coordination complexes with the versatile and biomimetic ligands 1,2,4-triazolo[1,5-a]pyrimidine (tp), 5,7-dimethyl-1,2-4- triazolo(dmtp) and 7-amine-1-2, 4-trizolo(7atp) all feature dinuclear building units, which are the preferred motif, independently of the counter-anion used.

TL;DR: The trinuclear secondary building unit (SBU) is constructed from chelating and alcoholate-O-bridging chiral amino alcoholate (amino alkoxido, μ-L) and terminal halide ligands (X) as mentioned in this paper.