Jerzy Zoń

TL;DR: In this article, cross-linking of arabinoxylans by ferulate dehydrodimers and incorporation of feruloylated arabinoxideylans into lignin were modelled with maize walls (Zea mays cv Black Mexican) containing 5.3-18.0 mg g−1 of total ferulates.

TL;DR: The synthesis, structural characterization, and functionality (framework interconversions together with proton conductivity) of an open-framework hybrid that combines Ca(2+) ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl)isophthalic acid (PiPhtA) is reported, highlighting the importance of internal H-bonding networks that determine conductivity properties of hybrid materials.

TL;DR: 1,3,5-Benzenetriphosphonic acid, H6BTP, was reacted hydrothermally with copper salts in the absence and presence of 4,4'-bipyridine (bpy), leading to three new organic-inorganic hybrid frameworks leading to a large channel-sized 3D framework.

TL;DR: Results from semi-empirical calculations combined with a proposed partial active site model showed a correlation between the experimental kinetic constants and the change in polarization of the pro-S Cbeta-H bond and heat of formation of the sigma complexes, thus making the electrophilic attack at the neutral aromatic ring plausible.