J
John F. Nixon
Researcher at University of Sussex
Publications - 380
Citations - 6088
John F. Nixon is an academic researcher from University of Sussex. The author has contributed to research in topics: Phosphaalkyne & Crystal structure. The author has an hindex of 34, co-authored 379 publications receiving 5897 citations. Previous affiliations of John F. Nixon include State University of Campinas.
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[3+2] Cycloaddition reactions of the phospha-alkyne, ButCP, with a transition metal trisulphide containing terminal thio ligands: syntheses, crystal and molecular structures of [W(η5-(C5Me5)(S)(S2PCtBu)]2 and [W(η5-(C5Me5)(S)(S2C2Ph2)]2
Sarah E d’Arbeloff,Peter B. Hitchcock,John F. Nixon,Takayuki Nagasawa,Hiroyuki Kawaguchi,Kazuyuki Tatsumi +5 more
TL;DR: The trisulphido complex [PPh4][W(η5-(C5Me5)(S)3] as discussed by the authors reacts with the phospha-alkyne ButCP and O2 to afford the dimeric complex [S2PCtBu]2.
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Synthesis and 31P and 195Pt NMR characterisation of the first binuclear platinum(I) complex [Pt2Cl2(μ-dppm)2(μ-ButCP)] containing a μ-parallel ligated phospha-alkyne
Saud I. Al-Resayes,John F. Nixon +1 more
TL;DR: In this paper, the first μ-parallel ligated phospha-alkyne was reported in the complex [Pt 2 Cl 2 (μ-dppm) 2 [μ-Bu t CP] whose structure has been elucidated by 31 p and 195 pt NMR studies.
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Coordination Chemistry of Unsaturated Organophosphorus Ligands
TL;DR: Similarities between phosphorus and carbon in un-saturated systems and their transition metal complexes are discussed in this paper, where the same authors also discuss the relationship between carbon and phosphorus.
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Electronic Structure and Bonding in Neutral and Dianionic Boradiphospholes: R′BC2P2R2 (R=H, tBu, R′=H, Ph)
Dandamudi Usharani,Dandamudi Usharani,Anne Poduska,John F. Nixon,Eluvathingal D. Jemmis,Eluvathingal D. Jemmis +5 more
TL;DR: The principal factors that affect the stability of three-, four-, and five-membered ring and acyclic geometrical and positional isomers of neutral and dianionic BC(2)P (2)H(3) isomers appear to be: 1) relative bond strengths, 2) availability of electrons for the empty 2p boron orbital and 3) steric effects of the tBu groups in the HBC( 2)P(2).
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Synthesis and variable temperature 31P NMR spectra of the cobalt, rhodium and iridium complexes [M(P(O)(OMe)2)(P(OMe)3)4] (M = Co, Rh, Ir)
Stanlei I. Klein,John F. Nixon +1 more
TL;DR: In this article, the results of variable temperature 31P NMR studies are described, and mechanistic implications are discussed, including the mechanistic implication of the dependence of the temperature on the temperature of the NMR signal.