J
John F. Nixon
Researcher at University of Sussex
Publications - 380
Citations - 6088
John F. Nixon is an academic researcher from University of Sussex. The author has contributed to research in topics: Phosphaalkyne & Crystal structure. The author has an hindex of 34, co-authored 379 publications receiving 5897 citations. Previous affiliations of John F. Nixon include State University of Campinas.
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Journal ArticleDOI
Novel transition metal phospha-alkyne complexes: tBuCP acting as a 6 electron donor ligand. Synthesis, crystal and molecular structure of [Co2(CO)6(μ-tBuCP)W(CO)5]
James C. T. R. Burckett-St. Laurent,Peter B. Hitchcock,Harold W. Kroto,M. F. Meidine,John F. Nixon +4 more
TL;DR: In this paper, a single crystal X-ray diffraction study of [Co 2 (CO) 6 (μ- t BuCP)W(CO) 5 ] was performed and it was shown that phospha-alkyne behaves as a 6e donor.
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Photoelectron spectroscopy and electronic structure of the hexaphosphatitanocene [Ti(η5-P3C2But2)2]
TL;DR: In this article, the He I photoelectron spectrum of [Ti(η5-P3C2But2)2] was assigned and a detailed orbital analysis was presented.
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Photoelectron spectra of the phospha-alkynes: 3,3-dimethyl-1-phosphabutyne ButCP and phenylphosphaethyne, PhCP
James C. T. R. Burckett-St. Laurent,Michael A. King,Harold W. Kroto,John F. Nixon,R. J. Suffolk +4 more
TL;DR: In this article, photoelectron spectra of the phospha-alkynes ButCP and PhCP were obtained by comparison with spectra from related species and with the aid of ab initio SCF molecular orbital calculations.
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A study of the molecular and electronic structures of the indium(I) phospholyls [In(η5-P2C3But3)] and [In(η5-P3C2But2)] by X-ray diffraction, photoelectron spectroscopy and density functional theory
Guy K. B. Clentsmith,F. Geoffrey N. Cloke,Matthew D. Francis,Jennifer C. Green,Peter B. Hitchcock,John F. Nixon,James L. Suter,David M. Vickers +7 more
TL;DR: In this article, the crystal and molecular structures of [In(η5-P2C3But3)] were reported by comparison with related systems and with the aid of density functional calculations of the ionisation energies.
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Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl2(PEt3)(PPhCPhCPh)], cis-[Ptl(PPh3)(CPhCPhPPhMe)] and [(Et3P)2Pt(CPhCPhPPh)W(CO)5]
Salih S. Al Juaid,Duncan Carmichael,Peter B. Hitchcock,Angela Marinetti,François Mathey,John F. Nixon +5 more
TL;DR: The phosphirene ring system undergoes unidentate ligation and/or insertion reactions with a variety of platinum metal complexes as discussed by the authors, and insertion reactions also occur with the [W(CO)5] adduct of 1 Detailed NMR and single-crystal X-ray studies on [PtCl2(PEt3)([graphic omitted]Ph)] and [Et3P] confirm the nature of both types of complexes.