K
K. Cory MacLeod
Researcher at Yale University
Publications - 23
Citations - 974
K. Cory MacLeod is an academic researcher from Yale University. The author has contributed to research in topics: Cyclopentadienyl complex & Pyridine. The author has an hindex of 16, co-authored 22 publications receiving 863 citations. Previous affiliations of K. Cory MacLeod include University of British Columbia & University of Rochester.
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Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.
TL;DR: The identities of all atoms in the iron-molybdenum cofactor of nitrogenase have finally been elucidated, and the discovery of a carbide has generated new questions and targets for coordination chemists.
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A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage
TL;DR: This is the first molecular system that both breaks and forms the triple bond of N2 at room temperature and highlights the ability of multi-iron species to decrease the energy barriers associated with the activation of strong bonds.
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Reversible C-C bond formation between redox-active pyridine ligands in iron complexes.
Thomas R. Dugan,Eckhard Bill,K. Cory MacLeod,Gemma J. Christian,Ryan E. Cowley,William W. Brennessel,Shengfa Ye,Frank Neese,Patrick L. Holland +8 more
TL;DR: Structural, spectroscopic, and computational studies on the complex with 4-tert-butylpyridine ((tBu)py) indicate that the S = 3/2 species is a resonance hybrid between descriptions as high-spin iron(II) with antiferromagnetic coupling to a pyridine anion radical and high- spin iron(I).
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Stepwise N–H bond formation from N2-derived iron nitride, imide and amide intermediates to ammonia
TL;DR: The pathway from N2 to NH3 at low-coordinate iron complexes is shown through crystallographic and spectroscopic characterization of intermediates, including bridging nitride, imide, and amides, including proton-coupled electron transfer.
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Cyclopentadienyl Chromium β-Diketiminate Complexes: Initiators, Ligand Steric Effects, and Deactivation Processes in the Controlled Radical Polymerization of Vinyl Acetate
Yohan Champouret,K. Cory MacLeod,Ulrich Baisch,Brian O. Patrick,Kevin M. Smith,Rinaldo Poli,Rinaldo Poli +6 more
TL;DR: In this article, a new compound CpCr(nacnacAr,Ar′) was synthesized and used in polymerization experiments in addition to the previously known analogues with Ar = Ar′ = xyl, 1, or dipp, 5.