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Keiji Maruoka

Researcher at Kyoto University

Publications -  907
Citations -  24733

Keiji Maruoka is an academic researcher from Kyoto University. The author has contributed to research in topics: Catalysis & Enantioselective synthesis. The author has an hindex of 76, co-authored 885 publications receiving 22433 citations. Previous affiliations of Keiji Maruoka include Sumitomo Chemical & Nagasaki University.

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Design of Bowl‑Shaped N ‑Hydroxyimide Derivatives as New Organoradical Catalysts for Site‑Selective C(sp 3 )−H Bond Functionalization Reactions

TL;DR: A series of new bowl-shaped N -hydroxyimide derivatives has been designed and used as selective organoradical catalysts that exhibit excellent site-selectivity in the amination of benzylic C(sp 3 )-H bonds in aromatic hydrocarbon substrates.
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Rate Acceleration of Solid-Liquid Phase-Transfer Catalysis by Rotor-Stator Homogenizer

TL;DR: In this paper, a rotor-stator homogenizer was used to accelerate phase-transfer reactions in solid-liquid phase transfer reactions, and a considerably high turnover frequency was observed.
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A Synthetic Route to Sodium α-Aminoalkanesulfinates and Their Application in the Generation of α-Aminoalkyl Radicals for Radical Addition Reactions

TL;DR: Treatment of sodium α-aminoalkanesulfinates with (diacetoxyiodo)benzene easily generated the corresponding α- aminoalkyl radicals under mild conditions, which were then applied in radical 1,2-addition to imines, radical 1-4-add addition to electron-deficient olefins, and radical addition/cyclization to 2-isocyanobiphenyls.
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Catalytic Asymmetric Alkylation of 3‐Aryl‐Substituted Oxindoles to give 3,3‐Disubstituted Oxindoles under Phase‐Transfer Conditions

TL;DR: An efficient enantioselective method for the construction of all-carbon quaternary stereocenters from 3-aryl-substituted oxindoles via asymmetric phase-transfer alkylation has been developed.