L
Laurence J. Hardwick
Researcher at University of Liverpool
Publications - 129
Citations - 16720
Laurence J. Hardwick is an academic researcher from University of Liverpool. The author has contributed to research in topics: Raman spectroscopy & Lithium. The author has an hindex of 39, co-authored 106 publications receiving 14274 citations. Previous affiliations of Laurence J. Hardwick include Paul Scherrer Institute & University of Southampton.
Papers
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Journal ArticleDOI
Li-O2 and Li-S batteries with high energy storage.
Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
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Reactions in the Rechargeable Lithium–O2 Battery with Alkyl Carbonate Electrolytes
Stefan Freunberger,Yi Chen,Zhangquan Peng,John M. Griffin,Laurence J. Hardwick,Fanny Bardé,Petr Novák,Peter G. Bruce +7 more
TL;DR: Mechanisms are proposed for the reactions on discharge and charge that are consistent with the widely observed voltage gap in Li-O(2) cells.
Journal ArticleDOI
The Lithium–Oxygen Battery with Ether-Based Electrolytes
Stefan Freunberger,Yi Chen,Nicholas E. Drewett,Laurence J. Hardwick,Fanny Bardé,Fanny Bardé,Peter G. Bruce +6 more
TL;DR: It is demonstrated that ether-based electrolytes are not suitable for rechargeable Li–O2 cells, although the ethers are more stable than the organic carbonates, the Li2O2 that forms on the first discharge is accompanied by electrolyte decomposition, to give a mixture of Li2CO3, HCO2 Li, CH3CO2Li, polyethers/ esters, CO2, and H2O.
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Lithium Diffusion in Graphitic Carbon
Kristin A. Persson,Kristin A. Persson,Vijay A. Sethuraman,Vijay A. Sethuraman,Laurence J. Hardwick,Laurence J. Hardwick,Yoyo Hinuma,Yoyo Hinuma,Ying Shirley Meng,Ying Shirley Meng,Anton Van der Ven,Venkat Srinivasan,Robert Kostecki,Gerbrand Ceder +13 more
TL;DR: In this paper, the authors used the Devanathan- Stachurski electrochemical methodology combined with ab initio computations to deconvolute and quantify the mechanism of lithium ion diffusion in highly oriented pyrolytic graphite (HOPG).
Journal ArticleDOI
Oxygen Reactions in a Non-Aqueous Li+ Electrolyte†
Zhangquan Peng,Stefan Freunberger,Laurence J. Hardwick,Yi Chen,Vincent Giordani,Fanny Bardé,Petr Novák,Duncan Graham,Jean-Marie Tarascon,Peter G. Bruce +9 more
TL;DR: In situ spectroscopic data are presented that provide direct evidence that LiO2 is indeed an intermediate on O2 reduction, which then disproportionates to the final product Li2O2.