L
Leo A. Paquette
Researcher at Ohio State University
Publications - 484
Citations - 6138
Leo A. Paquette is an academic researcher from Ohio State University. The author has contributed to research in topics: Ring (chemistry) & Total synthesis. The author has an hindex of 36, co-authored 484 publications receiving 6021 citations. Previous affiliations of Leo A. Paquette include Heidelberg University.
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Studies Directed to the Synthesis of the Unusual Cardiotoxic Agent Kalmanol. Enantioselective Construction of the Advanced Tetracyclic 7-Oxy-5,6-dideoxy Congener
TL;DR: In this paper, the first synthesis of a highly functionalized B-homo-C-nor grayanotoxin closely related to kalmanol was reported, and an enantiocontrolled route to the diquinane sector was first developed from (4R)-(+)-tert-butyldimethylsiloxycyclopentenone by taking advantage of the Michael acceptor properties of this enone and an α,β-unsaturated ester subsequently derived from it, viz., 4 → 7 → 8.3.
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Intercalation of Multiple Carbon Atoms between the Carbonyls of α-Diketones
TL;DR: The reaction of open-chain or cyclic α-diketones with specific ω-alkenyl organometallics leads readily under the proper conditions to 1,2-diols bonded to terminal olefinic chains as mentioned in this paper.
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Molecular ladders constituted of laterally-fused 1,4-cyclohexadiene subunits. Open-chain models of the [n]beltenes.
Ron J. Graham,Leo A. Paquette +1 more
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Electronic control of stereoselectivity. 9. The stereochemical course of electrophilic additions to aryl-substituted benzobicyclo[2.2.2]octadienes
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Exploratory Synthetic Studies Involving the Tricyclo[9.3.0.02,8]tetradecane Ring System Peculiar to the Cyathins
Karl R. Dahnke,Leo A. Paquette +1 more
TL;DR: In this article, an improved preparation of 2-methylene-1,3-dithiolane was shown to undergo inverse-electron-demand Diels-Alder cycloaddition to tropone.