L
Leo A. Paquette
Researcher at Ohio State University
Publications - 484
Citations - 6138
Leo A. Paquette is an academic researcher from Ohio State University. The author has contributed to research in topics: Ring (chemistry) & Total synthesis. The author has an hindex of 36, co-authored 484 publications receiving 6021 citations. Previous affiliations of Leo A. Paquette include Heidelberg University.
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Relevance of oxyanion stereochemistry to chirality transfer in anionic oxy-cope rearrangements
TL;DR: Geometrically and optically pure (3R,5E)- and 1,5-heptadien-3-ols undergo anionic oxy-Cope rearrangement under the exclusice control of oxyanion orientation with a 58-64% preference for equatorial oxygen as mentioned in this paper.
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Electronic control of stereoselectivity. 1. Singlet oxygen and related electrophilic additions to aryl-substituted 7-isopropylidenebenzonorbornenes
TL;DR: In this article, the authors bestimmen wahrscheinlich hauptsachlich zwei Mechanismen das anti:syn-Verhaltnis im Produktgemisch.
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Pestalotiopsin A. Side Chain Installation and Exhaustive Probing of Olefin Metathesis as a Possible Tool for Elaborating the Cyclononene Ring
TL;DR: A program directed toward an asymmetric synthesis of pestalotiopsin A is described, which involved the introduction of terminal double bonds in anticipation of the fact that the (E)-cyclononene substructure could be realized by ring-closing metathesis.
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Cascade Rearrangements Following Twofold Addition of Alkenyl Anions to Squarate Esters
TL;DR: The double 1,2-addition of alkenyl, cycloalkenyl, and alkynyllithium reagents to squarate esters constitutes a very expedient method for rapidly increasing structural complexity with formation of polycyclic end products.
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Asymmetric functionalization of conformationally distinctive Cs-symmetric cis-[n.3.1] bicyclic ketones. Definition of the absolute course of enantio- and diastereodifferentiation
T. L. Underiner,Leo A. Paquette +1 more
TL;DR: In this article, the four C s -symmetric cis[n.3.1] bicyclic ketones were acetalized with (R,R)-2,4-pentanediol, and the resulting derivatives were cleaved with triisobutylaluminum (TRIBAL).