M
Masahiro Murakami
Researcher at Kyoto University
Publications - 694
Citations - 20243
Masahiro Murakami is an academic researcher from Kyoto University. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 72, co-authored 672 publications receiving 18238 citations. Previous affiliations of Masahiro Murakami include University of Tokyo & Gifu University.
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Vinylcyclopropanation of Olefins via 3‐Methoxy‐1‐propenylrhodium(I).
TL;DR: In this paper, a cyclization reaction forming vinylcyclopropanes was developed wherein an alkenylrhodium possessing a methoxy group at the allylic position as a potential leaving group acts as an allylic carbene equivalent.
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Synthesis of α,β,γ,δ-Unsaturated Imines from N-Sulfonyl-1,2,3-triazoles and Allenes Through Rhodium-Catalyzed Cyclopropanation and Thermal Rearrangement.
TL;DR: In this paper, α,β,γ,δ-Unsaturated imines are synthesized from N-sulfonyl-1,2,3-triazoles and allenes.
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Stereoselective Synthesis of syn‐Configured α‐Allenols by Rhodium‐Catalyzed Reaction of Alkynyl Oxiranes with Arylboronic Acids.
Tomoya Miura,Masahiko Shimada,Paula de Mendoza,Carl Deutsch,Norbert Krause,Masahiro Murakami +5 more
TL;DR: In this article, a rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids affords syn-configured α-allenols with high diastereoselectivity.
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Alkyllithium-Mediated Anomalous Trimerization of 2,6-Xylyl Isocyanide.
TL;DR: The reaction of alkyllithium with 2,6-xylyl isocyanide led to the trimerization of the isoscelynide to afford an indole derivative as discussed by the authors.
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Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols.
TL;DR: In this paper, isocyanates (I) with benzylic or allylic alcohols in the presence of a Pd-catalyst results in a cyclization and [1,3]-rearrangement sequence to give the title compounds.