M
Masahiro Murakami
Researcher at Kyoto University
Publications - 694
Citations - 20243
Masahiro Murakami is an academic researcher from Kyoto University. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 72, co-authored 672 publications receiving 18238 citations. Previous affiliations of Masahiro Murakami include University of Tokyo & Gifu University.
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Synthesis of silafluorenes by iridium-catalyzed [2 + 2 + 2] cycloaddition of silicon-bridged diynes with alkynes.
TL;DR: In this article, the skeleton of a silicon-bridged 1,6-diynes was constructed by the [2 + 2 + 2] cycloaddition of tetraynes.
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Stereoselective intramolecular bis-silylation of alkenes promoted by a palladium-isocyanide catalyst leading to polyol synthesis
Masahiro Murakami,Michinori Suginome,Keisuke Fujimoto,Hiroshi Nakamura,Pher G. Andersson,Yoshihiko Ito +5 more
TL;DR: Stereoselective Intramolecular Bis-Silylation of Alkenes Promoted by a Palladium-Isocyanide Catalyst Leading to Polyol Synthesis.
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Palladium(II) acetate-tert-alkyl isocyanide as a highly efficient catalyst for the inter- and intramolecular bis-silylation of carbon-carbon triple bonds
TL;DR: A new catalyst, palladium (II) acetate-tert-alkyl isocyanide, permitted the intermolecular bis-silylation of alkynes by otherwise unreactive disilanes as mentioned in this paper.
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Rhodium(i)-catalyzed successive double cleavage of carbon-carbon bonds of strained spiro cyclobutanones
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Cleavage of C-C and C-Si σ-bonds and their intramolecular exchange.
TL;DR: C-C and C-Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst and results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.