M
Mireille Blanchard-Desce
Researcher at University of Rennes
Publications - 116
Citations - 8655
Mireille Blanchard-Desce is an academic researcher from University of Rennes. The author has contributed to research in topics: Two-photon absorption & Hyperpolarizability. The author has an hindex of 49, co-authored 111 publications receiving 8312 citations. Previous affiliations of Mireille Blanchard-Desce include University of Bordeaux & California Institute of Technology.
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Journal ArticleDOI
Large First Hyperpolarizabilities in Push-Pull Polyenes by Tuning of the Bond Length Alternation and Aromaticity
Seth R. Marder,Lap-Tak Cheng,Bruce G. Tiemann,Andrienne C. Friedli,Mireille Blanchard-Desce,Joseph W. Perry,Jørgen Skindhøj +6 more
TL;DR: In this paper, the design strategies demonstrated in chromophores that when incorporated into poled-polymer electrooptic modulators exhibited significant enhancements in electro-optic coefficients relative to polymers containing the commonly used dye Disperse Red-1.
Journal ArticleDOI
Enhanced two-photon absorption of organic chromophores: theoretical and experimental assessments ∗∗
Francesca Terenziani,Claudine Katan,Ekaterina Badaeva,Sergei Tretiak,Mireille Blanchard-Desce +4 more
TL;DR: In this paper, a review of experimental and theoretical methodologies allowing detailed investigation and analysis of two-photon absorption properties of organic chromophores is presented, focusing on symmetric and asymmetric donor/acceptor substitution and branching.
Journal ArticleDOI
Distance-Dependent Fluorescence Quenching on Gold Nanoparticles Ensheathed with Layer-by-Layer Assembled Polyelectrolytes
Grégory F. Schneider,Gero Decher,Nicolas Nerambourg,Raïssa Praho,Martinus H. V. Werts,Mireille Blanchard-Desce +5 more
TL;DR: UV-visible spectroscopy and transmission electron microscopy confirm that the particle suspensions of fluorescently labeled core/shell nanoparticles are stable at all stages of their construction and strongly distance-dependent fluorescence quenching in these particle systems.
Journal ArticleDOI
Charge instability in quadrupolar chromophores: symmetry breaking and solvatochromism.
TL;DR: A model based on a few-state description of the charge-transfer processes characterizing the low-energy physics of multipolar molecular systems is developed, offering important clues to understand basic properties of materials of interest for NLO and energy-harvesting applications.
Journal ArticleDOI
Large Quadratic Hyperpolarizabilities with Donor–Acceptor Polyenes Exhibiting Optimum Bond Length Alternation: Correlation Between Structure and Hyperpolarizability
Mireille Blanchard-Desce,Valérie Alain,Peter V. Bedworth,Seth R. Marder,Alain Fort,Claude Runser,Marguerite Barzoukas,Sonja Lebus,Rüdiger Wortmann +8 more
TL;DR: In this article, the reduction of the bond length alternation (BLA) in the polyenic chain has been investigated, and unprecedented quadratic hyperpolarizabilities (p) have been achieved (up to p(0) =I500 x 10-30esu) by reduction.