Summary form only given. Fundamental processes in atoms, molecules, as well as condensed matter are triggered or mediated by the motion of electrons inside or between atoms. Electronic dynamics on atomic length scales tends to unfold within tens to thousands of attoseconds (1 attosecond [as] = 10-18 s). Recent breakthroughs in laser science are now opening the door to watching and controlling these hitherto inaccessible microscopic dynamics. The key to accessing the attosecond time domain is the control of the electric field of (visible) light, which varies its strength and direction within less than a femtosecond (1 femtosecond = 1000 attoseconds). Atoms exposed to a few oscillations cycles of intense laser light are able to emit a single extreme ultraviolet (XUV) burst lasting less than one femtosecond. Full control of the evolution of the electromagnetic field in laser pulses comprising a few wave cycles have recently allowed the reproducible generation and measurement of isolated sub-femtosecond XUV pulses, demonstrating the control of microscopic processes (electron motion and photon emission) on an attosecond time scale. These tools have enabled us to visualize the oscillating electric field of visible light with an attosecond "oscilloscope", to control single-electron and probe multi-electron dynamics in atoms, molecules and solids. Recent experiments hold promise for the development of an attosecond X-ray source, which may pave the way towards 4D electron imaging with sub-atomic resolution in space and time.

Attosecond Physics

Researchers report sub-angstrom fundamental-wavelength lasing at the SPring-8 Angstrom Compact Free-Electron Laser in Japan. The output has a maximum power of more than 10 GW, a pulse duration of 10−14 s and a lasing wavelength of 0.634 A.

A compact X-ray free-electron laser emitting in the sub-ångström region

High-harmonic generation by focusing a femtosecond laser onto a gas is a well-known method of producing coherent extreme-ultraviolet (EUV) light. This nonlinear conversion process requires high pulse intensities, greater than 10(13) W cm(-2), which are not directly attainable using only the output power of a femtosecond oscillator. Chirped-pulse amplification enables the pulse intensity to exceed this threshold by incorporating several regenerative and/or multi-pass amplifier cavities in tandem. Intracavity pulse amplification (designed not to reduce the pulse repetition rate) also requires a long cavity. Here we demonstrate a method of high-harmonic generation that requires no extra cavities. This is achieved by exploiting the local field enhancement induced by resonant plasmons within a metallic nanostructure consisting of bow-tie-shaped gold elements on a sapphire substrate. In our experiment, the output beam emitted from a modest femtosecond oscillator (100-kW peak power, 1.3-nJ pulse energy and 10-fs pulse duration) is directly focused onto the nanostructure with a pulse intensity of only 10(11) W cm(-2). The enhancement factor exceeds 20 dB, which is sufficient to produce EUV wavelengths down to 47 nm by injection with an argon gas jet. The method could form the basis for constructing laptop-sized EUV light sources for advanced lithography and high-resolution imaging applications.

High-harmonic generation by resonant plasmon field enhancement

A new automated multi-function core scanning instrument, named ITRAX, has been developed that records optical, radiographic and elemental variations from sediment half cores up to 1.8 m long at a resolution as fine as 200 ?m. An intense micro-X-ray beam focused through a flat capillary waveguide is used to irradiate samples to enable both X-radiography and X-ray fluorescence (XRF) analysis. Data are acquired incrementally by advancing a split core, via a programmable stepped motor drive, through the flat, rectangular-section X-ray beam. Traditional XRF determination of element composition in sediments provides high-quality data, but it takes a considerable time and normally consumes gram quantities of material that is often only available in limited quantities. The ITRAX core scanner non-destructively collects optical and X-radiographic images, and provides high-resolution elemental profiles that are invaluable for guiding sample selection for further (destructive) detailed sampling. This paper presents a description of the construction, characteristics and capabilities of the ITRAX system. High-resolution ITRAX data obtained from sediment cores are also presented and compared with results from traditional wavelength-dispersive XRF analysis at lower resolution. Finally, some recent technical developments linked to the second-generation ITRAX are presented.

ITRAX: description and evaluation of a new multi-function X-ray core scanner

心臓病診療プラクティス 16. 心不全を癒す

Generating X-rays that have the properties of laser light has been a long-standing goal for experimental science. Here we describe the emission of highly collimated, spatially coherent X-rays, at a wavelength of about 1 nanometre and at photon energies extending to 1.3 kiloelectronvolts, from atoms that have been ionized by a 5-femtosecond laser pulse. This means that a laboratory source of laser-like, kiloelectronvolt X-rays, which will operate on timescales relevant to many chemical, biological and materials problems, is now within reach.

Laser technology: source of coherent kiloelectronvolt X-rays.

High-order harmonic generation from atoms ionized by femtosecond laser pulses has been a promising approach for the development of coherent short-wavelength sources. However, the realization of a powerful harmonic X-ray source has been hampered by a phase velocity mismatch between the driving wave and its harmonics, limiting their coherent build-up to a short propagation length and thereby compromising the efficiency of a single source. Here, we report coherent superposition of laser-driven soft-X-ray (SXR) harmonics, at wavelengths of 2–5 nm, generated in two successive sources by one and the same laser pulse. Observation of constructive and destructive interference suggests the feasibility of quasi-phase-matched SXR harmonic generation by a focused laser beam in a gas medium of modulated density. Our proof-of-concept study opens the prospect of enhancing the photon flux of SXR harmonic sources to levels enabling researchers to tackle a range of applications in physical as well as life sciences.

Coherent superposition of laser-driven soft-X-ray harmonics from successive sources

Total reflection x-ray fluorescence analysis (TXRF) is a special energy-dispersive x-ray analytical technique extending XRF down to the ultra trace element range. Detection limits of picograms or nanograms per gram levels are reached with x-ray tube excitation. Using synchrotron radiation as excitation source, femtogram levels are detectable, particularly important for Si wafer surface analysis. TXRF is specially suited for applications in which only a very small amount of sample is available, as only a few micrograms are required for the analysis. In this review, an overview of theoretical principles, advantages, instrumentation, quantification and application is given. Chemical analysis as well as surface analysis including depth profiling and thin-film characterization is described. Special research results on extension to low-Z elements, excitation with synchrotron radiation and x-ray absorption spectroscopy (XAS) for chemical speciation at trace levels are reviewed. Copyright © 2007 John Wiley & Sons, Ltd.

Peter Wobrauschek

Papers

Laser technology: source of coherent kiloelectronvolt X-rays.

Coherent superposition of laser-driven soft-X-ray harmonics from successive sources

Total reflection x‐ray fluorescence analysis—a review

Spatial distribution of the trace elements zinc, strontium and lead in human bone tissue

A method for quantitative X-ray fluorescence analysis in the nanogram region