R
Richard D. Adams
Researcher at University of South Carolina
Publications - 688
Citations - 12489
Richard D. Adams is an academic researcher from University of South Carolina. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 45, co-authored 665 publications receiving 12134 citations. Previous affiliations of Richard D. Adams include University at Buffalo & Texas A&M University.
Papers
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Journal ArticleDOI
Platinum-osmium cluster complexes from the addition of Pt(PBut3) groups to Os3(CO)12.
TL;DR: Three new compounds, PtOs(3)(CO)(12)(PBu(t)(3)) (10), Pt(2)Os (3)( CO)(12) (2) (11), and Pt(3)Os(1) (3) (12), have been obtained from the reaction of Pt(PBu (t)(t) with Os( 3)(CO) (9).
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Cluster synthesis. 32. Hydrogen-rich metal cluster complexes from the reaction of octadecacarbonyltetraosmiumdiplatinum with hydrogen. Synthesis and molecular structures of PtOs5(CO)16(.mu.-H)6, Pt2Os5(CO)17(.mu.-H)6, PtOs6(CO)18(.mu.-H)8, and Pt2Os7(CO)23(.mu.-H)8
TL;DR: From the reaction of Pt 2 Os 4 (CO) 18 with hydrogen at 25°C/100 atm, four new hydrogen-rich platinum osmium carbonyl cluster complexes were obtained as discussed by the authors.
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Cluster synthesis. 30. New platinum-osmium carbonyl cluster complexes from the reaction of Os3(CO)10(NCMe)2 with bis(cyclooctadiene)platinum
TL;DR: In this paper, two new platinum-osmium carbonyl cluster complexes, Pt 2 Os 3 (CO) 10 (COD) 2 and PtO 3 CO 8 H 11 ) (μ-H) were obtained from the reaction of Os 3 CO 10 (NCMe) 2 with Pt(COD 2) 2 at 25°C.
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Syntheses and Reactivity of Organohletallic Cohlpounds Containing Ihlinoacyl Ligands. Reactions of Hletal Carbonyl Anions with Ihlidoyl Halides
TL;DR: In this paper, the authors showed that weakly nucleophilic anions such as tetracarbonylcobaltate induce a head-to-tail coupling reaction of two imidoyl groupings via the incorporation of two anions.
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Reactions of thioethers with Mn(2)(CO)(7)(mu-S(2)) proceed with CO displacement and insertion of the sulfur atom into the Mn-Mn bond.
TL;DR: Compounds 3, 5, and 7 have similar structures in which the thioether ligand has replaced the bridging carbonyl ligand of 2 and its sulfur atom has been inserted into the manganese-manganese bond.