R
Richard D. Adams
Researcher at University of South Carolina
Publications - 688
Citations - 12489
Richard D. Adams is an academic researcher from University of South Carolina. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 45, co-authored 665 publications receiving 12134 citations. Previous affiliations of Richard D. Adams include University at Buffalo & Texas A&M University.
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Journal ArticleDOI
Cluster Fragmentation and Facile Cleavage of Phenyl Groups from the SnPh3 Ligand in Reactions of Os3(CO)11(SnPh3)(μ-H) with CO and HSnPh3
TL;DR: Two new cluster complexes, Os3(CO)12(Ph)(μ3-SnPh), 8 (35% yield) and Os4(CO), 16(μ4-Sn), 9 (10% yield), were formed when the complex of 6 with HSnPh3 was heated to reflux in toluene solvent under a CO atmosphere.
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Chirality retention in twist rearrangements of pseudooctahedral molybdenum and tungsten complexes
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New route to dehydroannulenes by coupling linear polyynes using ruthenium carbonyl.
Richard D. Adams,Qu B,Smith +2 more
TL;DR: The reaction of FcC⋮CC⋷CC⊂CCⓂCFc with Ru3(CO)12 has yielded the novel cyclic polyyne, which contains a planar cyclic tetrayne with two Ru2( CO)6 metallacycles and four ferrocenyl groups lie on the same side of the ring.
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Rhenium-bismuth carbonyl cluster compounds.
TL;DR: The reaction of Re(2)(CO)(8)[mu-eta(2)-C( H)=C(H)Bu(n)](mu-H) with BiPh(3) in heptane solvent at reflux yielded three new compounds, which contain two fused rings and a quadruply bridging BiPhBiPh ligand that contains a Bi-Bi bond.
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Isocyanide insertion reactions. The reaction of Mn(CO)/sub 4/CNCH/sub 3/ anion with iodomethane and the crystal and molecular structure of (CH/sub 3/)N == C(CH/sub 3/)(CH/sub 3/)C == N(CH/sub 3/)Mn(CO)/sub 3/Mn(CO)/sub 3/
TL;DR: In this article, the cyclic compounds (CH/sub 3/)N == C(R)Fe(CO)/sub 3/Fe( CO)/sub 4/(CNCH/Sub 3/)/sup -/ with CH/sub3/I were analyzed crystallographically.