S
Sarah E. Caldwell
Researcher at Duke University
Publications - 6
Citations - 1187
Sarah E. Caldwell is an academic researcher from Duke University. The author has contributed to research in topics: Nitrosation & Nitrosyl chloride. The author has an hindex of 5, co-authored 6 publications receiving 1140 citations.
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Mechanisms of free radical oxidation of unsaturated lipids
TL;DR: The mechanisms of these primary reaction steps has been the focus of extensive research over the past fifty years, and the current level of understanding of these transformations is the subject of this review.
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The mechanism of the 3,2 allylperoxyl rearrangement : a radical-dioxygen pair reaction that proceeds with stereochemical memory
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An allyl radical-dioxygen caged pair mechanism for cis-allylperoxyl rearrangements
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Preparation of Unsymmetrically Labeled Hydroperoxides. A Hydroxamate Ester−Nitrosation Approach
TL;DR: In this paper, the reaction of O-tertiary alkyl aryl hydroxamate esters with nitrosyl chloride gives O-TERTiary alkal aryls peresters that can be hydrolyzed to the hydroperoxide.