Journal ArticleDOI
An allyl radical-dioxygen caged pair mechanism for cis-allylperoxyl rearrangements
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This article is published in Journal of the American Chemical Society.The article was published on 1992-11-01. It has received 26 citations till now. The article focuses on the topics: Aliphatic compound & Solvent effects.read more
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Journal ArticleDOI
Mechanisms of free radical oxidation of unsaturated lipids
TL;DR: The mechanisms of these primary reaction steps has been the focus of extensive research over the past fifty years, and the current level of understanding of these transformations is the subject of this review.
Journal ArticleDOI
Mechanism of free radical oxygenation of polyunsaturated fatty acids by cyclooxygenases.
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Free radical oxidation of polyunsaturated lipids: New mechanistic insights and the development of peroxyl radical clocks.
TL;DR: The current understanding of the mechanism of unsaturated lipid peroxidation is presented, effectively updating the Account on the same topic published 25 years ago, and a powerful peroxyl radical clock methodology is developed, which can be used to determine rate constants for reactions ofperoxyl radicals with molecules having rate constants ranging from 1 to 10 M(-1) s(-1).
OtherDOI
Lipid Oxidation: Theoretical Aspects
TL;DR: This chapter reviews initiation processes with a focus on differentiating rates, mechanisms, and specificity of radical formation; and it presents evidence for multiple propagation mechanisms that lead to different product mixes.
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Rearrangements of organic peroxides and related processes
TL;DR: This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides.